ArticleStructural dynamics (Melville, N.Y.)2016
Monitoring conical intersections in the ring opening of furan by attosecond stimulated X-ray Raman spectroscopy.
Article in Structural dynamics (Melville, N.Y.), 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 11 papers.
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Who cites it
11 citing papers in PubMed.
- Ultrafast metal-to-ligand electron transfer driven by bond shortening revealed through dual-edge computational X-ray spectroscopy.Communications chemistry · 2026Article
- Transient X‑ray Absorption Signatures of Photodissociation Pathways and Conical Intersection Dynamics in Phenol.JACS Au · 2026Article
- Light-Induced Persistent Electronic Chirality in Achiral Molecules Probed with Time-Resolved Electronic Circular Dichroism Spectroscopy.The journal of physical chemistry letters · 2025Article
- Capturing fingerprints of conical intersection: Complementary information of non-adiabatic dynamics from linear x-ray probes.Structural dynamics (Melville, N.Y.) · 2021Article
- Signatures of Conical Intersection Dynamics in the Time-Resolved Photoelectron Spectrum of Furan: Theoretical Modeling with an Ensemble Density Functional Theory Method.International journal of molecular sciences · 2021Article
- Vibronic Dynamics of Photodissociating ICN from Simulations of Ultrafast X-Ray Absorption Spectroscopy.Angewandte Chemie (International ed. in English) · 2020Article
- Ultrafast Spectroscopy of Photoactive Molecular Systems from First Principles: Where We Stand Today and Where We Are Going.Journal of the American Chemical Society · 2020Article
- Probing competing relaxation pathways in malonaldehyde with transient X-ray absorption spectroscopy.Chemical science · 2020Article
- Study of double core hole excitations in molecules by X-ray double-quantum-coherence signals: a multi-configuration simulation.Chemical science · 2016Article
- Time-resolved X-ray spectroscopies of chemical systems: New perspectives.Structural dynamics (Melville, N.Y.) · 2016Article
- Preface to Special Topic: Invited Papers of the 3rd International Conference on Ultrafast Structural Dynamics.Structural dynamics (Melville, N.Y.) · 2016Article
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Authors and funding
8 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Attosecond X-ray pulses are short enough to capture snapshots of molecules undergoing nonadiabatic electron and nuclear dynamics at conical intersections (CoIns). We show that a stimulated Raman probe induced by a combination of an attosecond and a femtosecond pulse has a unique temporal and spectral resolution for probing the nonadiabatic dynamics and detecting the ultrafast (∼4.5 fs) passage through a CoIn. This is demonstrated by a multiconfigurational self-consistent-field study of the dynamics and spectroscopy of the furan ring-opening reaction. Trajectories generated by surface hopping simulations were used to predict Attosecond Stimulated X-ray Raman Spectroscopy signals at reactant and product structures as well as representative snapshots along the conical intersection seam. The signals are highly sensitive to the changes in nonadiabatically coupled electronic structure and geometry.
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