Evidence map›Paper›PMID 26798780›Full record

ArticleStructural dynamics (Melville, N.Y.)2014

Probing ion-specific effects on aqueous acetate solutions: Ion pairing versus water structure modifications.

Tristan Petit, Kathrin M Lange, Gerrit Conrad, Kenji Yamamoto, Christoph Schwanke, Kai F Hodeck, Marcus Dantz, Tim Brandenburg, Edlira Suljoti, Emad F Aziz

Open access · goldAbstract read
In one paragraph

Article in Structural dynamics (Melville, N.Y.), 2014. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.

0numbers the graph read from it
0cells of the map it votes in
4citing papers in PubMed
3.1field-weighted citation impact, top 8% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

4 citing papers in PubMed, 26 citations in OpenAlex.

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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

10 authors at 2 institutions in 1 country.

Tristan PetitJoint Ultrafast Dynamics Lab in Solutions and at Interfaces (JULiq) , Helmholtz-Zentrum Berlin für Materialien und Energie, Albert-Einstein-Strasse 15, D-12489 Berlin, Germany.
Kathrin M LangeJoint Ultrafast Dynamics Lab in Solutions and at Interfaces (JULiq) , Helmholtz-Zentrum Berlin für Materialien und Energie, Albert-Einstein-Strasse 15, D-12489 Berlin, Germany.
Gerrit ConradJoint Ultrafast Dynamics Lab in Solutions and at Interfaces (JULiq) , Helmholtz-Zentrum Berlin für Materialien und Energie, Albert-Einstein-Strasse 15, D-12489 Berlin, Germany.
Kenji Yamamoto
Christoph SchwankeJoint Ultrafast Dynamics Lab in Solutions and at Interfaces (JULiq) , Helmholtz-Zentrum Berlin für Materialien und Energie, Albert-Einstein-Strasse 15, D-12489 Berlin, Germany.
Kai F HodeckJoint Ultrafast Dynamics Lab in Solutions and at Interfaces (JULiq) , Helmholtz-Zentrum Berlin für Materialien und Energie, Albert-Einstein-Strasse 15, D-12489 Berlin, Germany.
Marcus Dantz
Tim Brandenburg
Edlira SuljotiJoint Ultrafast Dynamics Lab in Solutions and at Interfaces (JULiq) , Helmholtz-Zentrum Berlin für Materialien und Energie, Albert-Einstein-Strasse 15, D-12489 Berlin, Germany.
Emad F Aziz
Helmholtz-Zentrum Berlin für Materialien und Energie · DEFreie Universität Berlin · DE

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The effect of monovalent cations (Li(+), K(+), NH4 (+), Na(+)) on the water structure in aqueous chloride and acetate solutions was characterized by oxygen K-edge X-ray absorption spectroscopy (XAS), X-ray emission spectroscopy, and resonant inelastic X-ray scattering (RIXS) of a liquid microjet. We show ion- and counterion dependent effects on the emission spectra of the oxygen K-edge, which we attribute to modifications of the hydrogen bond network of water. For acetates, ion pairing with carboxylates was also probed selectively by XAS and RIXS. We correlate our experimental results to speciation data and to the salting-out properties of the cations.

Identifiers

PMID26798780
PMCPMC4711606
OpenAlexW2039475299

What OpenQuestion holds

Textmetadata
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.