Evidence map›Paper›PMID 26756610›Full record

ArticleNano letters2016

Controlling Catalyst Bulk Reservoir Effects for Monolayer Hexagonal Boron Nitride CVD.

Sabina Caneva, Robert S Weatherup, Bernhard C Bayer, Raoul Blume, Andrea Cabrero-Vilatela, Philipp Braeuninger-Weimer, Marie-Blandine Martin, Ruizhi Wang, Carsten Baehtz, Robert Schloegl and 2 more

Abstract read
In one paragraph

Article in Nano letters, 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 22 papers.

0numbers the graph read from it
0cells of the map it votes in
22citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

22 citing papers in PubMed.

  1. Article
  2. Article
  3. Article
  4. Article
  5. Review
  6. Heterostructure Engineering of 2D Superlattice Materials for Electrocatalysis.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2022
    Review
  7. Article
  8. Review
  9. Article
  10. Article
  11. Article
  12. Article
  13. Article
  14. Article
  15. Inhibition of WildNanomaterials (Basel, Switzerland) · 2019
    Article
  16. Article
  17. Article
  18. Article
  19. Article
  20. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

12 authors.

Sabina CanevaDepartment of Engineering, University of Cambridge , JJ Thomson Avenue, CB3 0FA Cambridge, United Kingdom.
Robert S WeatherupDepartment of Engineering, University of Cambridge , JJ Thomson Avenue, CB3 0FA Cambridge, United Kingdom.
Bernhard C BayerDepartment of Engineering, University of Cambridge , JJ Thomson Avenue, CB3 0FA Cambridge, United Kingdom.
Raoul BlumeHelmholtz-Zentrum Berlin für Materialen und Energie , D-12489 Berlin, Germany.
Andrea Cabrero-VilatelaDepartment of Engineering, University of Cambridge , JJ Thomson Avenue, CB3 0FA Cambridge, United Kingdom.
Philipp Braeuninger-WeimerDepartment of Engineering, University of Cambridge , JJ Thomson Avenue, CB3 0FA Cambridge, United Kingdom.
Marie-Blandine MartinDepartment of Engineering, University of Cambridge , JJ Thomson Avenue, CB3 0FA Cambridge, United Kingdom.
Ruizhi WangDepartment of Engineering, University of Cambridge , JJ Thomson Avenue, CB3 0FA Cambridge, United Kingdom.
Carsten BaehtzInstitute of Radiation Physics, Helmholtz-Zentrum Dresden-Rossendorf , 01314 Dresden, Germany.
Robert SchloeglFritz Haber Institute , D-14195 Berlin-Dahlem, Germany.
Jannik C MeyerFaculty of Physics, University of Vienna , Boltzmanngasse 5, A-1090 Vienna, Austria.
Stephan HofmannDepartment of Engineering, University of Cambridge , JJ Thomson Avenue, CB3 0FA Cambridge, United Kingdom.

Funding

European Research Council 279342
6 · The paper itself

Abstract

Highly controlled Fe-catalyzed growth of monolayer hexagonal boron nitride (h-BN) films is demonstrated by the dissolution of nitrogen into the catalyst bulk via NH3 exposure prior to the actual growth step. This "pre-filling" of the catalyst bulk reservoir allows us to control and limit the uptake of B and N species during borazine exposure and thereby to control the incubation time and h-BN growth kinetics while also limiting the contribution of uncontrolled precipitation-driven h-BN growth during cooling. Using in situ X-ray diffraction and in situ X-ray photoelectron spectroscopy combined with systematic growth calibrations, we develop an understanding and framework for engineering the catalyst bulk reservoir to optimize the growth process, which is also relevant to other 2D materials and their heterostructures.

Indexed as

Ammonium CompoundsBoron CompoundsCatalysisIronKineticsNanostructuresNitrogenSurface PropertiesX-Ray DiffractionAmmonium CompoundsBoron Compoundsboron nitrideIronNitrogenammonia (NH3)borazine (HBNH)3chemical vapor deposition (CVD)hexagonal boron nitride (h-BN)iron (Fe)

Identifiers

PMID26756610
PMCPMC4751513

What OpenQuestion holds

Textmetadata
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.