ArticleNature communications2016
The hydrogen-bond network of water supports propagating optical phonon-like modes.
Article in Nature communications, 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 17 papers.
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Who cites it
17 citing papers in PubMed.
- A Golden-Ratio Ladder and a Delocalisation-Saturated Participation Bridge for the Hydrogen-Bond Network of Liquid Water.Molecules (Basel, Switzerland) · 2026Article
- Proton shuttling at electrochemical interfaces under alkaline hydrogen evolution.Nature communications · 2026Article
- Predictive Quantum Vibrational Spectra through Active Learning 4G-NNPs.The journal of physical chemistry letters · 2026Article
- Lifting Hofmeister's Curse: Impact of Cations on Diffusion, Hydrogen Bonding, and Clustering of Water.Journal of the American Chemical Society · 2024Article
- Ultrafast and Nanoscale Energy Transduction Mechanisms and Coupled Thermal Transport across Interfaces.ACS nano · 2023Review
- Combinational Vibration Modes in HThe journal of physical chemistry. B · 2023Article
- The birth and evolution of solvated electrons in the water.Proceedings of the National Academy of Sciences of the United States of America · 2023Article
- Dielectric Properties of Water in Charged Nanopores.The journal of physical chemistry. B · 2022Article
- Terahertz pump-probe of liquid water at 12.3 THz.Physical chemistry chemical physics : PCCP · 2022Article
- Review
- Influence of Water Polarization Caused by Phonon Resonance on Catalytic Activity of Enolase.ACS omega · 2021Article
- Structural evolution of water and hydroxyl groups during thermal, mechanical and chemical treatment of high purity natural quartz.RSC advances · 2020Article
- The nano-structural inhomogeneity of dynamic hydrogen bond network of TIP4P/2005 water.Scientific reports · 2020Article
- Towards Intense THz Spectroscopy on Water: Characterization of Optical Rectification by GaP, OH1, and DSTMS at OPA Wavelengths.Materials (Basel, Switzerland) · 2020Article
- Exploring the behaviour of water in glycerol solutions by using delayed luminescence.PloS one · 2018Article
- An Analog Macroscopic Technique for Studying Molecular Hydrodynamic Processes in Dense Gases and Liquids.Journal of visualized experiments : JoVE · 2017Article
- Article
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2 authors.
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Abstract
The local structure of liquid water as a function of temperature is a source of intense research. This structure is intimately linked to the dynamics of water molecules, which can be measured using Raman and infrared spectroscopies. The assignment of spectral peaks depends on whether they are collective modes or single-molecule motions. Vibrational modes in liquids are usually considered to be associated to the motions of single molecules or small clusters. Using molecular dynamics simulations, here we find dispersive optical phonon-like modes in the librational and OH-stretching bands. We argue that on subpicosecond time scales these modes propagate through water's hydrogen-bond network over distances of up to 2 nm. In the long wavelength limit these optical modes exhibit longitudinal-transverse splitting, indicating the presence of coherent long-range dipole-dipole interactions, as in ice. Our results indicate the dynamics of liquid water have more similarities to ice than previously thought.
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