ArticleNanoscale research letters2015
Fabrication of Vertical Array CNTs/Polyaniline Composite Membranes by Microwave-Assisted In Situ Polymerization.
Article in Nanoscale research letters, 2015. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
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Who cites it
6 citing papers in PubMed, 33 citations in OpenAlex.
- Novel Carboxylated PANI/MWCNT Dispersions and Impregnated Cellulose Substrates for Photocatalytic Methylene Blue Dye Removal.Nanomaterials (Basel, Switzerland) · 2026Article
- Sustainable Hydrothermal and Solvothermal Synthesis of Advanced Carbon Materials in Multidimensional Applications: A Review.Materials (Basel, Switzerland) · 2021Review
- Article
- Dispersing gold nanoparticles on thiolated polyaniline-multiwalled carbon nanotubes for development of an indole-3-acetic acid amperometric immunosensor.Nanoscale advances · 2019Article
- Enhanced electrocatalytic performance of platinum nanoparticles on thiolated polyaniline-multiwalled carbon nanotubes for methanol oxidation.RSC advances · 2018Article
- Development of Self-Assembled Nanoribbon Bound Peptide-Polyaniline Composite Scaffolds and Their Interactions with Neural Cortical Cells.Bioengineering (Basel, Switzerland) · 2018Article
Corrections and comments
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Authors and funding
6 authors at 1 institution in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
A vertical array carbon nanotubes (VACNTs)/polyaniline (PANi) composite membrane was prepared by microwave-assisted in situ polymerization. With microwave assistance, the morphology of PANi revealed a smaller diameter and denser connection. Meanwhile, thermogravimetric analysis showed improved thermal stability of microwave-assisted PANi for higher molecular weight. Focused ion beam thinning method was used to cut the VACNTs/PANi membrane into dozen-nanometer thin strips along the cross-sectional direction, and transmission electron microscopy observation showed seamless deposition of PANi between VACNT gaps, without damaging the vertical status of CNTs. Meanwhile, stronger conjugate interaction between the quinoid ring of PANi and VACNTs of the composite membrane were prompted by microwave-assisted in situ polymerization. By using nanoindentation technology, the VACNTs/PANi composite membrane showed exponential increasing of modulus and hardness. Meanwhile, the elasticity was also improved, which was proved by the calculated plastic index. The results can provide helpful guidance for seamlessly infiltrating matrix into CNT array and also demonstrate the importance of structural hierarchy for getting proper behavior of nanostructures.
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