ArticleAngewandte Chemie (International ed. in English)2016
Catalytic Borylative Opening of Propargyl Cyclopropane, Epoxide, Aziridine, and Oxetane Substrates: Ligand Controlled Synthesis of Allenyl Boronates and Alkenyl Diboronates.
Article in Angewandte Chemie (International ed. in English), 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 15 papers.
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Who cites it
15 citing papers in PubMed.
- Pd-Catalyzed C─C Bond Borylation of Biphenylenes Leading to Tri-Ortho-Substituted Biaryls.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Electrochemical synthesis of allenyl silanes and allenyl boronic esters.Nature communications · 2025Article
- Rare Gold-Catalyzed 4-Organic letters · 2024Article
- AChemical science · 2023Article
- Iron-Catalyzed Borylation of Propargylic Acetates for the Synthesis of Multisubstituted Allenylboronates.Chemistry (Weinheim an der Bergstrasse, Germany) · 2023Article
- Copper-Catalyzed Ring-Opening Reactions of Alkyl Aziridines with BMolecules (Basel, Switzerland) · 2021Article
- C-Boron Enolates Enable Palladium Catalyzed Carboboration of Internal 1,3-Enynes.Angewandte Chemie (International ed. in English) · 2021Article
- Deciphering the Chameleonic Chemistry of Allenols: Breaking the Taboo of a Onetime Esoteric Functionality.Chemical reviews · 2021Article
- Cu-catalyzed C-C bond formation of vinylidene cyclopropanes with carbon nucleophiles.Chemical science · 2019Article
- Catalyst-controlled regiodivergent ring-opening C(spChemical science · 2019Article
- Copper-catalyzed 1,4-alkylarylation of 1,3-enynes with masked alkyl electrophiles.Chemical science · 2019Article
- Copper-catalyzed synthesis of allenylboronic acids. Access to sterically encumbered homopropargylic alcohols and amines by propargylboration.Chemical science · 2018Article
- Catalytic, Enantioselective Synthesis of Allenyl Boronates.ACS catalysis · 2018Article
- Enantioselective Synthesis of Trisubstituted Allenyl-B(pin) Compounds by Phosphine-Cu-Catalyzed 1,3-Enyne Hydroboration. Insights Regarding Stereochemical Integrity of Cu-Allenyl Intermediates.Journal of the American Chemical Society · 2018Article
- Catalytic Borylative Opening of Propargyl Cyclopropane, Epoxide, Aziridine, and Oxetane Substrates: Ligand Controlled Synthesis of Allenyl Boronates and Alkenyl Diboronates.Angewandte Chemie (International ed. in English) · 2016Article
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Abstract
A new copper-catalyzed reaction for the stereo- and regioselective synthesis of alkenyl diboronates and allenyl boronates is presented. In this process propargyl derivatives of strained three/four-membered rings were employed as substrates and B2pin2 was used as the boronate source. Selective formation of the alkenyl diboronate versus the allenyl boronate products was controlled by the choice of phosphine ligand.
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