ArticleActa crystallographica. Section E, Crystallographic communications2015
Crystal structure of aceto-nitrile-[η(6)-1-methyl-4-(1-methyl-eth-yl)benzene][1-(pyrimidin-2-yl)-3H-indol-1-ium-2-yl-κ(2) N,C]ruthenium(II) bis-(hexa-fluorido-anti-monate).
Article in Acta crystallographica. Section E, Crystallographic communications, 2015. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
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2 citing papers in PubMed.
- Derivatization of 2,1,3-Benzothiadiazole via Regioselective C-H Functionalization and Aryne Reactivity.The Journal of organic chemistry · 2024Article
- Chemotherapeutic Activities of New ηMolecules (Basel, Switzerland) · 2024Article
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Abstract
In the title compound, [Ru(C10H14)(C12H9N3)(CH3CN)][SbF6]2, the ruthenium(II) cation is η (6)-coordinated by the para-cymene ligand with a Ru-centroid(η (6)-benzene) distance of 1.746 (2) Å. Furthermore, ruthenium coordinations to the C and N atoms of the pyrimidyl indole ligand are found to be 1.986 (4) and 2.082 (3) Å, respectively. The typical piano-stool coordination environment is saturated with an aceto-nitrile solvent mol-ecule with a Ru-N distance of 2.044 (3) Å. The indolyl ligand is protonated at the C3 position with the N=C imine bond length appropriate to that of related 3H-indole-based complexes. In the crystal, the complex cation is linked to the SbF6 (-) ions through weak C-H⋯F hydrogen bonds.
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