Evidence map›Paper›PMID 26594075›Full record

ArticleDyes and pigments : an international journal2015

Steady State and Time Resolved Fluorescence Studies of Azadioxatriangulenium (ADOTA) Fluorophore in Silica and PVA Thin Films.

Rahul Chib, Sangram Raut, Sunil Shah, Beata Grobelna, Irina Akopova, Ryan Rich, Thomas Just Sørensen, Bo W Laursen, Hanna Grajek, Zygmunt Gryczynski and 1 more

Open access · greenAbstract read
In one paragraph

Article in Dyes and pigments : an international journal, 2015. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.

0numbers the graph read from it
0cells of the map it votes in
4citing papers in PubMed
1.3field-weighted citation impact, top 22% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

4 citing papers in PubMed, 13 citations in OpenAlex.

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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

11 authors at 5 institutions in 3 countries.

Rahul ChibDepartment of Cell Biology and Immunology, Center for Fluorescence Technologies and Nanomedicine, University of North Texas Health Science Center, Fort Worth, TX 76107,USA.
Sangram RautDepartment of Cell Biology and Immunology, Center for Fluorescence Technologies and Nanomedicine, University of North Texas Health Science Center, Fort Worth, TX 76107,USA. ; Department of Physics and Astronomy, Texas Christian University, Fort Worth, TX, 76129, USA.
Sunil ShahDepartment of Cell Biology and Immunology, Center for Fluorescence Technologies and Nanomedicine, University of North Texas Health Science Center, Fort Worth, TX 76107,USA.
Beata GrobelnaFaculty of Chemistry, University of Gdańsk, Wita Stwosza 63, 80-952 Gdańsk, Poland.
Irina AkopovaDepartment of Cell Biology and Immunology, Center for Fluorescence Technologies and Nanomedicine, University of North Texas Health Science Center, Fort Worth, TX 76107,USA.
Ryan RichDepartment of Cell Biology and Immunology, Center for Fluorescence Technologies and Nanomedicine, University of North Texas Health Science Center, Fort Worth, TX 76107,USA.
Thomas Just SørensenNano-Science Center and Department of Chemistry University of Copenhagen, Universitetsparken 5, DK2100 København Ø, Denmark.
Bo W LaursenNano-Science Center and Department of Chemistry University of Copenhagen, Universitetsparken 5, DK2100 København Ø, Denmark.
Hanna GrajekDepartment of Physics and Biophysics, University of Warmia and Mazury in Olsztyn, 10-719, Poland.
Zygmunt GryczynskiDepartment of Cell Biology and Immunology, Center for Fluorescence Technologies and Nanomedicine, University of North Texas Health Science Center, Fort Worth, TX 76107,USA. ; Department of Physics and Astronomy, Texas Christian University, Fort Worth, TX, 76129, USA.
Ignacy GryczynskiDepartment of Cell Biology and Immunology, Center for Fluorescence Technologies and Nanomedicine, University of North Texas Health Science Center, Fort Worth, TX 76107,USA.
University of North Texas Health Science Center · USUniversity of Copenhagen · DKUniversity of North Texas · USUniversity of Gdańsk · PLUniversity of Warmia and Mazury in Olsztyn · PL

Funding

Novel Fluorophores for Molecular and Cellular ImagingR01EB012003 · NIBIB · UNIVERSITY OF NORTH TEXAS HLTH SCI CTR · PI GRYCZYNSKI, ZYGMUNT, YU, YIHUA BRUCE · 2011 to 2014
$1.8M
NIBIB NIH HHS R01 EB012003
6 · The paper itself

Abstract

A cationic azadioxatriangulenium (ADOTA) dye was entrapped in silica thin films obtained by the sol-gel process and in poly (vinyl) alcohol (PVA) thin films. Azadioxatriangulenium is a red emitting fluorophore with a long fluorescence lifetime of ~20 ns. The fluorescent properties of azadioxatriangulenium in silica thin films and PVA films were studied by means of steady-state and time resolved fluorescence techniques. We have found that the azadioxatriangulenium entrapped in silica thin film has a wider fluorescence lifetime distribution (Lorentzian distribution), lower fluorescence efficiencies, shorter lifetimes compared to Azadioxatriangulenium in a PVA film. The local environment of azadioxatriangulenium molecules in the silica thin film is rich with water and ethanol, which creates the possibility of forming excited state aggregates due to high concentration of dye within a small confined area. In contrast to the PVA matrices, the porous silica films allow restricted rotations of Azadioxatriangulenium molecules, which result in faster and complex fluorescence anisotropy decays suggesting energy migration among dye molecules.

Indexed as

AzadioxatrianguleniumFluorophoreLorentzian lifetime distributionLuminescenceSol-gel process

Identifiers

PMID26594075
PMCPMC4648278
OpenAlexW2076509808

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.