ArticleJournal of the American Chemical Society2015
A Concise Approach to Paxilline Indole Diterpenes.
Article in Journal of the American Chemical Society, 2015. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 32 papers.
What it found
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Who cites it
32 citing papers in PubMed.
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- Natural Product Synthesis Enabled by Radical-Polar Crossover Reactions.The Journal of organic chemistry · 2025Review
- Molecular complexity as a driving force for the advancement of organic synthesis.Nature reviews. Chemistry · 2024Review
- Total syntheses of (-)-macrocalyxoformins A and B and (-)-ludongnin C.Nature communications · 2024Article
- Directed Hydrogen Atom Transfer for Selective Reactions of Polyenols.Journal of the American Chemical Society · 2024Article
- Fe/Thiol Cooperative Hydrogen Atom Transfer Olefin Hydrogenation: Mechanistic Insights That Inform Enantioselective Catalysis.Journal of the American Chemical Society · 2024Article
- Engaging Alkenes in Metallaphotoredox: A Triple Catalytic, Radical Sorting Approach to Olefin-Alcohol Cross-Coupling.Journal of the American Chemical Society · 2024Article
- Hydrogen-Atom-Transfer-Initiated Radical/Polar Crossover Annulation Cascade for Expedient Access to Complex Tetralins.Angewandte Chemie (International ed. in English) · 2023Article
- Asymmetric Total Synthesis of Illisimonin A.Journal of the American Chemical Society · 2023Article
- Synthesis of Pleuromutilin.Journal of the American Chemical Society · 2022Article
- Synthesis of rearranged indole diterpenes of the paxilline type.Natural product reports · 2022Review
- Convergent total synthesis of (+)-calcipotriol: A scalable, modular approach to vitamin D analogs.Proceedings of the National Academy of Sciences of the United States of America · 2022Article
- Synergistic Brønsted/Lewis acid catalyzed aromatic alkylation with unactivated tertiary alcohols or di-Chemical science · 2022Article
- Total Synthesis of Shearinines D and G: A Convergent Approach to Indole Diterpenoids.Angewandte Chemie (International ed. in English) · 2022Article
- New Methods and Strategies in the Synthesis of Terpenoid Natural Products.Accounts of chemical research · 2021Review
- Stereocontrolled Radical Bicyclizations of Oxygenated Precursors Enable Short Syntheses of Oxidized Abietane Diterpenoids.Journal of the American Chemical Society · 2021Article
- Methodologies for the synthesis of quaternary carbon centers via hydroalkylation of unactivated olefins: twenty years of advances.Beilstein journal of organic chemistry · 2021Review
- Divergent Total Syntheses of (-)-Pseudocopsinine and (-)-Minovincinine.The Journal of organic chemistry · 2020Article
- Reductive radical-polar crossover: traditional electrophiles in modern radical reactions.Chemical science · 2019Review
Corrections and comments
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Authors and funding
3 authors.
Funding
Abstract
A synthetic approach to paxilline indole diterpenes is described. The route to the pentacyclic core relies on a new regioselective alkenylation of ketones and a tandem radical addition-aldol reaction sequence to access vicinal quaternary stereocenters. Emindole SB, the simplest member of the family, is synthesized in 11 steps from commercially available material to demonstrate the application of this approach.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.