ArticleAngewandte Chemie (International ed. in English)2016
Iron-Catalyzed Direct Diazidation for a Broad Range of Olefins.
Article in Angewandte Chemie (International ed. in English), 2016. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 44 papers.
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Who cites it
44 citing papers in PubMed.
- Iron-Photocatalyzed Alkene Chloroaminoxylation: A Platform for Orthogonally Activatable Building Blocks.Angewandte Chemie (International ed. in English) · 2026Article
- Bromonium-catalyzed 1,2-diamination of various conjugated alkenes.Chemical science · 2026Article
- Three-component synthesis of β-thio tertiary alkylamines from simple alkenes via SScience advances · 2026Article
- Regio- and chemoselective catalytic partial transfer hydrogenation of quinolines by dinuclear aluminum species.Nature communications · 2025Article
- Iron-catalyzed three-component 1,2-azidoalkylation of conjugated dienesChemical science · 2025Article
- Recent Progress in Synthetic Applications of Hypervalent Iodine(III) Reagents.Chemical reviews · 2024Review
- Mechanochemistry Drives Alkene Difunctionalization via Radical Ligand Transfer and Electron Catalysis.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- Catalytic 1,1-diazidation of alkenes.Nature communications · 2024Article
- Simple, catalytic C(spChemical communications (Cambridge, England) · 2024Article
- Photocatalytic, modular difunctionalization of alkenes enabled by ligand-to-metal charge transfer and radical ligand transfer.Chemical science · 2023Article
- Photochemical iron-catalyzed decarboxylative azidation via the merger of ligand-to-metal charge transfer and radical ligand transfer catalysis.Chem catalysis · 2023Article
- Modular and practical diamination of allenes.Nature communications · 2023Article
- Radical ligand transfer: a general strategy for radical functionalization.Beilstein journal of organic chemistry · 2023Article
- Photochemical diazidation of alkenes enabled by ligand-to-metal charge transfer and radical ligand transfer.Nature communications · 2022Article
- Iron-mediated ligand-to-metal charge transfer enables 1,2-diazidation of alkenes.Nature communications · 2022Article
- Mechanochemical Approach towards Multi-Functionalized 1,2,3-Triazoles and Anti-Seizure Drug Rufinamide Analogs Using Copper Beads.Molecules (Basel, Switzerland) · 2022Article
- Selective desaturation of amides: a direct approach to enamides.Chemical science · 2022Article
- Synthesis of Unsymmetrical Vicinal Diamines via Directed Hydroamination.Organic letters · 2022Article
- Synthesis of FeAngewandte Chemie (International ed. in English) · 2022Article
- Selective Azidooxygenation of Alkenes Enabled by Photo-induced Radical Transfer Using Aryl-λACS omega · 2021Article
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Authors and funding
4 authors.
Funding
Abstract
Reported herein is a new iron-catalyzed diastereoselective olefin diazidation reaction which occurs at room temperature (1-5 mol% of catalysts and d.r. values of up to >20:1). This method tolerates a broad range of both unfunctionalized and highly functionalized olefins, including those that are incompatible with existing methods. It also provides a convenient approach to vicinal primary diamines as well as other synthetically valuable nitrogen-containing building blocks which are difficult to obtain with alternative methods. Preliminary mechanistic studies suggest that the reaction may proceed through a new mechanistic pathway in which both Lewis acid activation and iron-enabled redox-catalysis are crucial for selective azido-group transfer.
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