ArticleScientific reports2015
Multiblock copolymers exhibiting spatio-temporal structure with autonomous viscosity oscillation.
Article in Scientific reports, 2015. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
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Who cites it
4 citing papers in PubMed.
- Proteinoid Computing on Olivine Substrates.Langmuir : the ACS journal of surfaces and colloids · 2026Article
- Toward Dynamic Liquid Cell Scaffold: Photoreversible Ion Gels Exhibiting Light-Induced Sol-Gel Transitions.Macromolecular rapid communications · 2026Article
- Amoeba-like self-oscillating polymeric fluids with autonomous sol-gel transition.Nature communications · 2017Article
- Artificial cilia as autonomous nanoactuators: Design of a gradient self-oscillating polymer brush with controlled unidirectional motion.Science advances · 2016Article
Corrections and comments
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Authors and funding
4 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Here we report an ABA triblock copolymer that can express microscopic autonomous formation and break-up of aggregates under constant condition to generate macroscopic viscoelastic self-oscillation of the solution. The ABA triblock copolymer is designed to have hydrophilic B segment and self-oscillating A segment at the both sides by RAFT copolymerization. In the A segment, a metal catalyst of chemical oscillatory reaction, i.e., the Belousov-Zhabotinsky (BZ) reaction, is introduced as a chemomechanical transducer to change the aggregation state of the polymer depending on the redox states. Time-resolved DLS measurements of the ABA triblock copolymer confirm the presence of a transitional network structure of micelle aggregations in the reduced state and a unimer structure in the oxidized state. This autonomous oscillation of a well-designed triblock copolymer enables dynamic biomimetic softmaterials with spatio-temporal structure.
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Registered trials
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