ArticleNature communications2015
Unravelling structural ambiguities in lithium- and manganese-rich transition metal oxides.
Article in Nature communications, 2015. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 22 papers.
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Who cites it
22 citing papers in PubMed.
- Orbital Stabilization of Anionic Redox via Surface Restructuration for Li-Rich Mn-Based Layered Oxides.Angewandte Chemie (International ed. in English) · 2026Article
- 'Tug of war' between competing phases in Li-rich cathodes revealed by analytical electron microscopy.National science review · 2025Article
- Revealing the chemical separated two-phase structure in lithium-manganese-rich cathode.National science review · 2025Article
- Visualization of Tetrahedral Li in the Alkali Layers of Li-Rich Layered Metal Oxides.Journal of the American Chemical Society · 2024Article
- Influence of the Composition and Testing Modes on the Electrochemical Performance of Li-Rich Cathode Materials.Nanomaterials (Basel, Switzerland) · 2022Article
- Quantitative analysis of diffuse electron scattering in the lithium-ion battery cathode material LiIUCrJ · 2022Article
- Tuning the Electronic, Ion Transport, and Stability Properties of Li-rich Manganese-based Oxide Materials with Oxide Perovskite Coatings: A First-Principles Computational Study.ACS applied materials & interfaces · 2022Article
- Polymorphic GaNanoscale advances · 2022Article
- The Influence of Synthesis Method on the Local Structure and Electrochemical Properties of Li-Rich/Mn-Rich NMC Cathode Materials for Li-Ion Batteries.Nanomaterials (Basel, Switzerland) · 2022Article
- In situ multiscale probing of the synthesis of a Ni-rich layered oxide cathode reveals reaction heterogeneity driven by competing kinetic pathways.Nature chemistry · 2022Article
- Local-electrostatics-induced oxygen octahedral distortion in perovskite oxides and insight into the structure of Ruddlesden-Popper phases.Nature communications · 2021Article
- Atomic-scale unveiling of multiphase evolution during hydrated Zn-ion insertion in vanadium oxide.Nature communications · 2021Article
- Sequential delithiation behavior and structural rearrangement of a nanoscale composite-structured LiScientific reports · 2020Article
- Insight into the Structural Disorder in Honeycomb-Ordered Sodium-Layered Oxide Cathodes.iScience · 2020Article
- Local Electric-Field-Driven Fast Li Diffusion Kinetics at the Piezoelectric LiTaOAdvanced science (Weinheim, Baden-Wurttemberg, Germany) · 2020Article
- Anomalous metal segregation in lithium-rich material provides design rules for stable cathode in lithium-ion battery.Nature communications · 2019Article
- Elucidating anionic oxygen activity in lithium-rich layered oxides.Nature communications · 2018Article
- Domain Formation in Lithium-Rich Manganese-Nickel-Cobalt-Oxide Epitaxial Thin Films and Implications for Interpretation of Electrochemical Behavior.Thin solid films · 2018Article
- Local degradation pathways in lithium-rich manganese-nickel-cobalt-oxide epitaxial thin films.Journal of materials science · 2018Article
- Coupling between oxygen redox and cation migration explains unusual electrochemistry in lithium-rich layered oxides.Nature communications · 2017Article
Corrections and comments
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Authors and funding
6 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Although Li- and Mn-rich transition metal oxides have been extensively studied as high-capacity cathode materials for Li-ion batteries, the crystal structure of these materials in their pristine state is not yet fully understood. Here we apply complementary electron microscopy and spectroscopy techniques at multi-length scale on well-formed Li1.2(Ni0.13Mn0.54Co0.13)O2 crystals with two different morphologies as well as two commercially available materials with similar compositions, and unambiguously describe the structural make-up of these samples. Systematically observing the entire primary particles along multiple zone axes reveals that they are consistently made up of a single phase, save for rare localized defects and a thin surface layer on certain crystallographic facets. More specifically, we show the bulk of the oxides can be described as an aperiodic crystal consisting of randomly stacked domains that correspond to three variants of monoclinic structure, while the surface is composed of a Co- and/or Ni-rich spinel with antisite defects.
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