ArticleThe Journal of organic chemistry2015
Woodward-Hoffmann's Stereochemistry of Electrocyclic Reactions: From Day 1 to the JACS Receipt Date (May 5, 1964 to November 30, 1964).
Article in The Journal of organic chemistry, 2015. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
What it found
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Who cites it
6 citing papers in PubMed.
- Creating a Masterpiece. The Road to (and Beyond) Woodward and Hoffmann's 1969 Angewandte Chemie Treatise.Chemical record (New York, N.Y.) · 2026Review
- Woodward and Hoffmann on Secondary Orbital Interactions. How to Make a Fine Two-Course Meal from Leftovers.Chemical record (New York, N.Y.) · 2025Review
- Woodward and Hoffmann. Hoffmann and Woodward. A Close Collaboration Had Yet to Begin.Chemical record (New York, N.Y.) · 2025Review
- Going Beyond Woodward and Hoffmann's Electrocyclizations and Cycloadditions: Sigmatropic Rearrangements.Chemical record (New York, N.Y.) · 2024Review
- A 21st Century View of Allowed and Forbidden Electrocyclic Reactions.The Journal of organic chemistry · 2024Article
- Review
Corrections and comments
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Authors and funding
1 author.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The publication in January 1965 of the first Woodward-Hoffmann paper, The Stereochemistry of Electrocyclic Reactions, ushered into organic chemistry both an explanation of the stereochemistry and "allowedness" or "forbiddenness" of concerted reactions and an impetus for untold numbers of research projects. In the current paper, details of the collaboration between R. B. Woodward and R. Hoffmann, from when they first met to discuss the solution to the "no-mechanism problem" to the date their first paper was received in the offices of the Journal of the American Chemical Society, will be discussed and analyzed. The primary focus will be on the historically relevant extant documents from the early 1960s. These include Hoffmann's laboratory notebooks describing his research, including his extended Hückel calculations used to explain and predict the stereochemistry of electrocyclic reactions. Drafts of the Stereochemistry of Electrocyclic Reactions paper and letters and notes by Woodward, Jerome Berson, and others will further illuminate the development of this first Woodward-Hoffmann paper.
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Registered trials
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