ArticleChemistry (Weinheim an der Bergstrasse, Germany)2015
Active-Metal Template Synthesis of a Halogen-Bonding Rotaxane for Anion Recognition.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2015. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 13 papers.
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Who cites it
13 citing papers in PubMed, 52 citations in OpenAlex.
- Active Templating by Mechanochemistry.Organic letters · 2026Article
- Metal-Free Active Template: A Straightforward Route to 4-Aminopyridinium-Based Rotaxane Molecular Shuttles.Angewandte Chemie (International ed. in English) · 2026Article
- Squaramide-Based Heteroditopic [2]Rotaxanes for Sodium Halide Ion-Pair Recognition.Chemistry (Weinheim an der Bergstrasse, Germany) · 2023Article
- Halogen bonding and chalcogen bonding mediated sensing.Chemical science · 2022Review
- Damming an electronic energy reservoir: ion-regulated electronic energy shuttling in a [2]rotaxane.Chemical science · 2021Article
- A sensitive and selective BINOL based ratiometric fluorescence sensor for the detection of cyanide ions.RSC advances · 2021Article
- Active template rotaxane synthesis through the Ni-catalyzed cross-coupling of alkylzinc reagents with redox-active esters.Chemical science · 2019Article
- Chemical Consequences of the Mechanical Bond: A Tandem Active Template-Rearrangement Reaction.Angewandte Chemie (International ed. in English) · 2019Article
- Chirality in rotaxanes and catenanes.Chemical Society reviews · 2018Review
- A Fluorescent Ditopic Rotaxane Ion-Pair Host.Angewandte Chemie (International ed. in English) · 2018Article
- Efficient Multicomponent Active Template Synthesis of Catenanes.Journal of the American Chemical Society · 2018Article
- Porphyrinoid rotaxanes: building a mechanical picket fence.Chemical science · 2017Article
- High yielding synthesis of 2,2'-bipyridine macrocycles, versatile intermediates in the synthesis of rotaxanes.Chemical science · 2016Article
Corrections and comments
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Authors and funding
3 authors at 2 institutions in 2 countries.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The synthesis of an all-halogen-bonding rotaxane for anion recognition is achieved by using active-metal templation. A flexible bis-iodotriazole-containing macrocycle is exploited for the metal-directed rotaxane synthesis. Endotopic binding of a Cu(I) template facilitates an active-metal CuAAC iodotriazole axle formation reaction that captures the interlocked rotaxane product. Following copper-template removal, exotopic coordination of a more sterically demanding rhenium(I) complex induces an inversion in the conformation of the macrocycle component, directing the iodotriazole halogen-bond donors into the rotaxane's interlocked binding cavity to facilitate anion recognition.
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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.