ArticleJournal of the American Chemical Society2015
Long-Term Passivation of Strongly Interacting Metals with Single-Layer Graphene.
Article in Journal of the American Chemical Society, 2015. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 22 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
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Who cites it
22 citing papers in PubMed.
- Protected ultrathin amorphous tin by intercalation at the graphene/Ru interface.Nanoscale advances · 2026Article
- Confined Reactivity in the van der Waals Gap beneath Graphene: Supply-Limited Kinetics and Emergent Reaction Pathways.ACS nano · 2026Article
- Realizing Scalable Chemical Vapor Deposition of Monolayer Graphene Films on Iron with Concurrent Surface Hardening byACS applied materials & interfaces · 2026Article
- Structural Defects on Graphene Generated by Deposition of CoO: Effect of Electronic Coupling of Graphene.Materials (Basel, Switzerland) · 2024Article
- Enhanced copper anticorrosion from Janus-doped bilayer graphene.Nature communications · 2023Article
- Effects of thermal treatments on the hydrophobicity and anticorrosion properties of as-grown graphene coatings.RSC advances · 2021Article
- Graphene overcoats for ultra-high storage density magnetic media.Nature communications · 2021Article
- Graphene Coating Obtained in a Cold-Wall CVD Process on the Co-Cr Alloy (L-605) for Medical Applications.International journal of molecular sciences · 2021Article
- Intercalation of Mn in graphene/Cu(111) interface: insights to the electronic and magnetic properties from theory.Scientific reports · 2020Article
- Oxygen intercalation in PVD graphene grown on copper substrates: A decoupling approach.Applied surface science · 2020Article
- Crystal Orientation Dependent Oxidation Modes at the Buried Graphene-Cu Interface.Chemistry of materials : a publication of the American Chemical Society · 2020Article
- Polymerization driven monomer passage through monolayer chemical vapour deposition graphene.Nature communications · 2018Article
- Enhancing Graphene Protective Coatings by Hydrogen-Induced Chemical Bond Formation.ACS applied nano materials · 2018Article
- High-resistivity metal-oxide films through an interlayer of graphene grown directly on copper electrodes.Graphene technology · 2018Article
- Real-time oxide evolution of copper protected by graphene and boron nitride barriers.Scientific reports · 2017Article
- Catalyst Interface Engineering for Improved 2D Film Lift-Off and Transfer.ACS applied materials & interfaces · 2016Article
- In Situ Graphene Growth Dynamics on Polycrystalline Catalyst Foils.Nano letters · 2016Article
- In Situ Observations of Phase Transitions in Metastable Nickel (Carbide)/Carbon Nanocomposites.The journal of physical chemistry. C, Nanomaterials and interfaces · 2016Article
- Visualising the strain distribution in suspended two-dimensional materials under local deformation.Scientific reports · 2016Article
- Controlling Catalyst Bulk Reservoir Effects for Monolayer Hexagonal Boron Nitride CVD.Nano letters · 2016Article
Corrections and comments
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Authors and funding
8 authors.
Funding
Abstract
The long-term (>18 months) protection of Ni surfaces against oxidation under atmospheric conditions is demonstrated by coverage with single-layer graphene, formed by chemical vapor deposition. In situ, depth-resolved X-ray photoelectron spectroscopy of various graphene-coated transition metals reveals that a strong graphene-metal interaction is of key importance in achieving this long-term protection. This strong interaction prevents the rapid intercalation of oxidizing species at the graphene-metal interface and thus suppresses oxidation of the substrate surface. Furthermore, the ability of the substrate to locally form a passivating oxide close to defects or damaged regions in the graphene overlayer is critical in plugging these defects and preventing oxidation from proceeding through the bulk of the substrate. We thus provide a clear rationale for understanding the extent to which two-dimensional materials can protect different substrates and highlight the key implications for applications of these materials as barrier layers to prevent oxidation.
Identifiers
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.