ArticleAngewandte Chemie (International ed. in English)2015
Divergent Reactivity of Rhodium(I) Carbenes Derived from Indole Annulations.
Article in Angewandte Chemie (International ed. in English), 2015. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
3 citing papers in PubMed.
- β-Carbon functionalization of amines via α-amino Cu-carbenes.Science advances · 2026Article
- Discovery of 2,3'-diindolylmethanes as a novel class of PCSK9 modulators.Bioorganic & medicinal chemistry letters · 2019Article
- Fe(III)-Catalyzed Bicyclization of Yne-Allenones With Indoles for the Atom-Economic Synthesis of 3-Indolyl Cyclobutarenes.Frontiers in chemistry · 2018Article
Corrections and comments
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Authors and funding
7 authors.
Funding
Abstract
Rhodium(I) carbenes were generated from propargylic alcohol derivatives as the result of a dehydrative indole annulation. Depending on the choice of the electron-withdrawing group on the aniline nitrogen nucleophile, either a cyclopropanation product or dimerization product was obtained chemoselectively. Intramolecular hydroamidation occurred for the same type of propargylic alcohol derivatives when other transition-metal catalysts were employed.
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Registered trials
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