ArticleOrganic process research & development
Why You Really Should Consider Using Palladium-Catalyzed Cross-Coupling of Silanols and Silanolates.
Article in Organic process research & development. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 39 papers.
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Who cites it
39 citing papers in PubMed.
- Article
- Regioselective Synthesis of Benzylsilanols from Kobayashi-Type Reagents via C(spAngewandte Chemie (International ed. in English) · 2026Article
- Cobalt-Catalyzed Three-Component Reductive Coupling of Aldehydes, Allenes, and Aryl Halides.Organic letters · 2026Article
- Astatine-211-Towards In Vivo Stable Astatine-211 Labeled Radiopharmaceuticals and Their (Pre)Clinical Applications.Medicinal research reviews · 2026Review
- Single Photocatalytic Hydrosilylation of Alkenes for the Synthesis of Bis(silyl) and Silaboryl Alkanes.JACS Au · 2025Article
- Multifunctional chiral silanol ligands for enantioselective catalysis.Chemical science · 2025Article
- Recyclable and air-stable colloidal manganese nanoparticles catalyzed hydrosilylation of alkenes with tertiary silane.RSC advances · 2025Article
- Development of subtype-selective estrogen receptor modulators using the bis(4-hydroxyphenyl)silanol core as a stable isostere of bis(4-hydroxyphenyl)methanol.RSC advances · 2023Article
- Facile preparation of organosilanes from benzylboronates andChemical science · 2023Article
- Organogelation enables fast organolithium cross-coupling reactions in air.Chemical communications (Cambridge, England) · 2023Article
- Chiral spirosiladiphosphines: ligand development and applications in Rh-catalyzed asymmetric hydrosilylation/cyclization of 1,6-enynes with enhanced reactivity.Chemical science · 2023Article
- Palladium-catalyzed synthesis of 4-sila-4Chemical science · 2023Article
- Selective oxidation of silanes into silanols with water using [MnBr(CO)Chemical science · 2022Article
- Development of a General Method for the Hiyama-Denmark Cross-Coupling of Tetrasubstituted Vinyl Silanes.ACS catalysis · 2022Article
- Photocatalytic E→Z Contra-Thermodynamic Isomerization of Vinyl Silanes with Lewis Base.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Copper-Promoted Hiyama Cross-Coupling of Arylsilanes With Thiuram Reagents: A Facile Synthesis of Aryl Dithiocarbamates.Frontiers in chemistry · 2022Article
- Synthesis and Hydrogen-Bond Patterns of Aryl-Group Substituted Silanediols and -triols from Alkoxy- and Chlorosilanes.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Silacyclization through palladium-catalyzed intermolecular silicon-based C(spChemical science · 2021Article
- Selective Enzymatic Oxidation of Silanes to Silanols.Angewandte Chemie (International ed. in English) · 2020Article
- Palladium-Catalyzed Oxidative Dehydrosilylation for Contra-Thermodynamic Olefin Isomerization.ACS catalysis · 2020Article
Corrections and comments
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2 authors.
Funding
Abstract
The transition metal-catalyzed cross-coupling of organometallic nucleophiles derived from tin, boron, and zinc with organic electrophiles enjoys a preeminent status among modern synthetic methods for the formation of carbon-carbon bonds. In recent years, organosilanes have emerged as viable alternatives to the conventional reagents, with the added benefits of low cost, low toxicity and high chemical stability. However, silicon-based cross-coupling reactions often require heating in the presence of a fluoride source, which has significantly hampered their widespread acceptance. To address the "fluoride problem", a new paradigm for palladium-catalyzed, silicon-based cross-coupling reactions has been developed that employs a heretofore underutilized class of silicon reagents, the
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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.