ArticleAngewandte Chemie (International ed. in English)2015
Enantioselective Synthesis of Spiroindenes by Enol-Directed Rhodium(III)-Catalyzed C-H Functionalization and Spiroannulation.
Article in Angewandte Chemie (International ed. in English), 2015. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
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Who cites it
8 citing papers in PubMed.
- Electrochemical Enantioselective C-H Annulation by Achiral Rhodium(III)/Chiral Brønsted Base Domino Catalysis.ACS catalysis · 2024Article
- Synthesis of CFMolecules (Basel, Switzerland) · 2023Article
- Rh-Catalyzed [3+2] Annulation of Cyclic Ketimines and Alkynyl Chloride: A Strategy for Accessing Unsymmetrically Substituted and Highly Functionalizable Indenes.Organic letters · 2022Article
- Synthesis of Functionalized Isoquinolone Derivatives via Rh(III)-Catalyzed [4+2]-Annulation of Benzamides with Internal Acetylene-Containing α-CFMolecules (Basel, Switzerland) · 2022Article
- Electrooxidative palladium- and enantioselective rhodium-catalyzed [3 + 2] spiroannulations.Chemical science · 2022Article
- On the hydrolysis of diethyl 2-(perfluorophenyl)malonate.Beilstein journal of organic chemistry · 2020Article
- Chiral cyclopentadienyl RhChemical science · 2019Article
- Tailored trisubstituted chiral CpChemical science · 2018Article
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4 authors.
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Abstract
Chiral cyclopentadienyl rhodium complexes promote highly enantioselective enol-directed C(sp(2))-H functionalization and oxidative annulation with alkynes to give spiroindenes containing all-carbon quaternary stereocenters. High selectivity between two possible directing groups, as well as control of the direction of rotation in the isomerization of an O-bound rhodium enolate into the C-bound isomer, appear to be critical for high enantiomeric excesses.
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