ArticleAngewandte Chemie (International ed. in English)2015
A Stimuli-Responsive Rotaxane-Gold Catalyst: Regulation of Activity and Diastereoselectivity.
Article in Angewandte Chemie (International ed. in English), 2015. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 47 papers.
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Who cites it
47 citing papers in PubMed.
- Tangled Tail of Mechanically Interlocked Peptides.Journal of the American Chemical Society · 2026Review
- Structural Dependence of Catenand Effect: Thermodynamic and Kinetic Modulation of Catenane Coordination Properties via Ring-size and Exocyclic Substituent Variation.Angewandte Chemie (International ed. in English) · 2025Article
- A Redox-active Cyclometalated Platinum Ring Enables Synthetic Post-processing of a [2]Rotaxane.Angewandte Chemie (International ed. in English) · 2025Article
- Urea-Based [2]Rotaxanes as Effective Phase-Transfer Organocatalysts: Hydrogen-Bonding Cooperative Activation Enabled by the Mechanical Bond.Journal of the American Chemical Society · 2024Article
- An Inorganic Click Reaction for the Synthesis of Interlocked Molecules.Angewandte Chemie (International ed. in English) · 2023Article
- Cooperative Capture Synthesis of Functionalized Heterorotaxanes─Chemical Scope, Kinetics, and Mechanistic Studies.Journal of the American Chemical Society · 2023Article
- Dynamic Metalloporphyrin-Based [2]Rotaxane Molecular Shuttles Stimulated by Neutral Lewis Base and Anion Coordination.Chemistry (Weinheim an der Bergstrasse, Germany) · 2023Article
- Direct Detection of Hydrogen Bonds in Supramolecular Systems UsingJournal of the American Chemical Society · 2022Article
- A light-gated regulation of the reaction site by a cucurbit[7]uril macrocycle.Chemical science · 2022Article
- Emerging properties from mechanical tethering within a post-synthetically functionalised catenane scaffold.Chemical science · 2022Article
- Supramolecular Rotaxane-Based Multi-Modal Probes for Cancer Biomarker Imaging.Angewandte Chemie (International ed. in English) · 2022Article
- Anion-π Catalysis Enabled by the Mechanical Bond.Angewandte Chemie (International ed. in English) · 2022Article
- Templation and Concentration Drive Conversion Between a FeJournal of the American Chemical Society · 2022Article
- Mechanically Interlocked Chiral Self-Templated [2]Catenanes from 2,6-Bis(1,2,3-triazol-4-yl)pyridine (btp) Ligands.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Using the Mechanical Bond to Tune the Performance of a Thermally Activated Delayed Fluorescence Emitter*.Angewandte Chemie (International ed. in English) · 2021Article
- Spin-labelled mechanically interlocked molecules as models for the interpretation of biradical EPR spectra.Chemical science · 2021Article
- Enantioselective Alkoxycyclization of 1,6-Enynes with Gold(I)-Cavitands: Total Synthesis of Mafaicheenamine C.Angewandte Chemie (International ed. in English) · 2021Article
- Functional Rotaxanes in Catalysis.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Review
- Cyclization of interlocked fumaramides into β-lactams: experimental and computational mechanistic assessment of the key intercomponent proton transfer and the stereocontrolling active pocket.Chemical science · 2020Article
- Cross dehydrogenative C-O coupling catalysed by a catenane-coordinated copper(i).Chemical science · 2020Article
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3 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
A rotaxane-based Au catalyst was developed and the effect of the mechanical bond on its behavior was studied. Unlike the non-interlocked thread, the rotaxane requires a catalytically innocent cofactor, the identity of which significantly influences both the yield and diastereoselectivity of the reaction. Under optimized conditions, Au(I) (the catalyst), Ag(I) (to abstract the Cl(-) ligand), and Cu(I) (the cofactor) combine to produce a catalyst with excellent activity and selectivity.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.