Evidence map›Paper›PMID 26351671›Full record

ArticleProceedings of the National Academy of Sciences of the United States of America2015

Glass-to-cryogenic-liquid transitions in aqueous solutions suggested by crack healing.

Chae Un Kim, Mark W Tate, Sol M Gruner

Abstract read
In one paragraph

Article in Proceedings of the National Academy of Sciences of the United States of America, 2015. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.

0numbers the graph read from it
0cells of the map it votes in
5citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

5 citing papers in PubMed.

  1. Article
  2. Direct observation of reversible liquid-liquid transition in a trehalose aqueous solution.Proceedings of the National Academy of Sciences of the United States of America · 2022
    Article
  3. Experimental evidence of low-density liquid water upon rapid decompression.Proceedings of the National Academy of Sciences of the United States of America · 2018
    Article
  4. Diffusive dynamics during the high-to-low density transition in amorphous ice.Proceedings of the National Academy of Sciences of the United States of America · 2017
    Article
  5. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

3 authors.

Chae Un KimCornell High Energy Synchrotron Source (CHESS) and Macromolecular Diffraction Facility at CHESS (MacCHESS), Cornell University, Ithaca, NY 14853; Department of Physics, Ulsan National Institute of Science and Technology, Ulsan 689-798, Republic of Korea; cukim@unist.ac.kr.
Mark W TateLaboratory of Atomic and Solid State Physics, Cornell University, Ithaca, NY 14853;
Sol M GrunerCornell High Energy Synchrotron Source (CHESS) and Macromolecular Diffraction Facility at CHESS (MacCHESS), Cornell University, Ithaca, NY 14853; Laboratory of Atomic and Solid State Physics, Cornell University, Ithaca, NY 14853; Department of Physics, Cornell University, Ithaca, NY 14853; Kavli Institute at Cornell for Nanoscale Science, Cornell University, Ithaca, NY 14853.

Funding

Overall (pp. 40-62)P41GM103485 · NIGMS · CORNELL UNIVERSITY · PI CERIONE, RICHARD A. · 2012 to 2018
$15.5M
NIGMS NIH HHS GM103485NIGMS NIH HHS P41 GM103485
6 · The paper itself

Abstract

Observation of theorized glass-to-liquid transitions between low-density amorphous (LDA) and high-density amorphous (HDA) water states had been stymied by rapid crystallization below the homogeneous water nucleation temperature (∼235 K at 0.1 MPa). We report optical and X-ray observations suggestive of glass-to-liquid transitions in these states. Crack healing, indicative of liquid, occurs when LDA ice transforms to cubic ice at 160 K, and when HDA ice transforms to the LDA state at temperatures as low as 120 K. X-ray diffraction study of the HDA to LDA transition clearly shows the characteristics of a first-order transition. Study of the glass-to-liquid transitions in nanoconfined aqueous solutions shows them to be independent of the solute concentrations, suggesting that they represent an intrinsic property of water. These findings support theories that LDA and HDA ice are thermodynamically distinct and that they are continuously connected to two different liquid states of water.

Indexed as

GlassCrystallizationIceKineticsModels, TheoreticalOptics and PhotonicsPhase TransitionPressureSolutionsTemperatureThermodynamicsWaterX-Ray DiffractionIceSolutionsWaterfirst-order phase transitionglass-to-liquid transitionhigh-density amorphous icelow-density amorphous icequenched HDA

Identifiers

PMID26351671
PMCPMC4586858

What OpenQuestion holds

Textmetadata
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.