ArticleInorganic chemistry2015
Homolytic N-H activation of ammonia: hydrogen transfer of parent iridium ammine, amide, imide, and nitride species.
Article in Inorganic chemistry, 2015. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 25 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
25 citing papers in PubMed, 110 citations in OpenAlex.
- Metal-Ligand Cooperation in N-H Activation: Bridging Electron-Pushing Formalism and Energy Descriptors.Inorganic chemistry · 2025Article
- Molecular Models of Atomically Dispersed Uranium at MoSJournal of the American Chemical Society · 2024Article
- Oxidation-induced ambiphilicity triggers N-N bond formation and dinitrogen release in octahedral terminal molybdenum(v) nitrido complexes.Chemical science · 2024Article
- A crystalline aluminium-carbon-based ambiphile capable of activation and catalytic transfer of ammonia in non-aqueous media.Nature chemistry · 2024Article
- Quadratic Spin-Orbit Mechanism of the Electronic g-Tensor.Journal of chemical theory and computation · 2023Article
- Polarized Au(I)/Rh(I) bimetallic pairs cooperatively trigger ligand non-innocence and bond activation.Dalton transactions (Cambridge, England : 2003) · 2023Article
- Heavy metalla vinyl-cations show metal-Lewis acid cooperativity in reaction with small molecules (NHChemical science · 2023Article
- Facile conversion of ammonia to a nitride in a rhenium system that cleaves dinitrogen.Chemical science · 2022Article
- Nitrogen Atom Transfer Catalysis by Metallonitrene C-H Insertion: Photocatalytic Amidation of Aldehydes.Angewandte Chemie (International ed. in English) · 2022Article
- Cationic Effects on the Net Hydrogen Atom Bond Dissociation Free Energy of High-Valent Manganese Imido Complexes.Journal of the American Chemical Society · 2022Article
- Free Energies of Proton-Coupled Electron Transfer Reagents and Their Applications.Chemical reviews · 2022Review
- Article
- Activation of ammonia and hydrazine by electron rich Fe(ii) complexes supported by a dianionic pentadentate ligand platform through a common terminal Fe(iii) amido intermediate.Chemical science · 2020Article
- Reversible Hydride Migration from CAngewandte Chemie (International ed. in English) · 2020Article
- A hemilabile diphosphine pyridine pincer ligand:Polyhedron · 2020Article
- Catalytic NChemical reviews · 2020Review
- (Electro-)chemical Splitting of Dinitrogen with a Rhenium Pincer Complex.European journal of inorganic chemistry · 2020Article
- Interconversion of Phosphinyl Radical and Phosphinidene Complexes by Proton Coupled Electron Transfer.Angewandte Chemie (International ed. in English) · 2019Article
- Homogeneous electrocatalytic oxidation of ammonia to NProceedings of the National Academy of Sciences of the United States of America · 2019Article
- Mechanism of Chemical and Electrochemical NJournal of the American Chemical Society · 2018Article
Corrections and comments
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Authors and funding
7 authors at 3 institutions in 2 countries.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The redox series [Ir(n)(NHx)(PNP)] (n = II-IV, x = 3-0; PNP = N(CHCHPtBu2)2) was examined with respect to electron, proton, and hydrogen atom transfer steps. The experimental and computational results suggest that the Ir(III) imido species [Ir(NH)(PNP)] is not stable but undergoes disproportionation to the respective Ir(II) amido and Ir(IV) nitrido species. N-H bond strengths are estimated upon reaction with hydrogen atom transfer reagents to rationalize this observation and are used to discuss the reactivity of these compounds toward E-H bond activation.
Identifiers
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.