ArticleJournal of the American Chemical Society2015
Catalytic Alkene Carboaminations Enabled by Oxidative Proton-Coupled Electron Transfer.
Article in Journal of the American Chemical Society, 2015. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 71 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
71 citing papers in PubMed, 295 citations in OpenAlex.
- Oxidative PCET-Triggered Benzylic C─H Iminolactonization via 1,5-HAT/Cyclization Enabled by Cage-Confined Photocatalysis.Angewandte Chemie (International ed. in English) · 2026Article
- From reagents to feedstocks: reprogramming heteroatom-containing molecules in modern organic synthesis.Molecular diversity · 2026Review
- Multisite Proton-Coupled Electron Transfer at a Keggin-Type Polyoxotungstate.Journal of the American Chemical Society · 2026Article
- Plasmonic Hot-Carrier Redox Enables Proton-Coupled Electron Transfer at C─H Bonds.Angewandte Chemie (International ed. in English) · 2026Article
- Direct generation of nitrogen-centered radicals via non-covalent interaction between Cu complexes and BiVONature communications · 2025Article
- Article
- Trisubstituted Alkenes as Valuable Building Blocks.Molecules (Basel, Switzerland) · 2025Review
- Enhanced Photoredox Activity in Nitrogen-Doped Carbon Nitride for Heterogeneous Nitrogen and Oxygen Radical Reactions.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Modular Synthesis of Dehydroprolines by an Energy-Transfer Enabled Cloke-Wilson Rearrangement.Angewandte Chemie (International ed. in English) · 2025Article
- Electrochemical cyclization of alkynes to construct five-membered nitrogen-heterocyclic rings.Beilstein journal of organic chemistry · 2025Review
- Total synthesis of bicyclomahanimbine by Cu(ii)-promoted photoredox process.RSC advances · 2024Article
- Photodetachment photoelectron spectroscopy shows isomer-specific proton-coupled electron transfer reactions in phenolic nitrate complexes.Communications chemistry · 2024Article
- Decoupling Plasmonic Hot Carrier from Thermal Catalysis via Electrode Engineering.Nano letters · 2024Article
- Photoredox-catalyzed intramolecular nucleophilic amidation of alkenes with β-lactams.Beilstein journal of organic chemistry · 2024Article
- Photocatalytic α-alkylation of carbamates with vinyl azaarenes.ARKIVOC : free online journal of organic chemistry · 2024Article
- Isotopic Fractionation as a Mechanistic Probe in Light-Driven C-H Bond Exchange Reactions.Journal of the American Chemical Society · 2023Article
- A Proton-Coupled Electron Transfer Strategy to the Redox-Neutral Photocatalytic COThe Journal of organic chemistry · 2023Article
- Modular synthesis of unsaturated aza-heterocycles via copper catalyzed multicomponent cascade reaction.iScience · 2023Article
- Highly Selective Radical Relay 1,4-Oxyimination of Two Electronically Differentiated Olefins.Journal of the American Chemical Society · 2022Article
- Exploiting photoredox catalysis for carbohydrate modification through C-H and C-C bond activation.Nature reviews. Chemistry · 2022Review
11 more citing papers are in PubMed but not listed here.
Corrections and comments
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Authors and funding
2 authors at 1 institution in 1 country.
Funding
Abstract
Here we describe a dual catalyst system comprised of an iridium photocatalyst and weak phosphate base that is capable of both selectively homolyzing the N-H bonds of N-arylamides (bond dissociation free energies ∼ 100 kcal/mol) via concerted proton-coupled electron transfer (PCET) and mediating efficient carboamination reactions of the resulting amidyl radicals. This manner of PCET activation, which finds its basis in numerous biological redox processes, enables the formal homolysis of a stronger amide N-H bond in the presence of weaker allylic C-H bonds, a selectivity that is uncommon in conventional molecular H atom acceptors. Moreover, this transformation affords access to a broad range of structurally complex heterocycles from simple amide starting materials. The design, synthetic scope, and mechanistic evaluation of the PCET process are described.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.