ReviewMolecules (Basel, Switzerland)2015
The Emergence of Quinone Methides in Asymmetric Organocatalysis.
Review in Molecules (Basel, Switzerland), 2015. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 37 papers.
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Who cites it
37 citing papers in PubMed.
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- Recent developments of α-nitroketones/α‑nitro-α,β-unsaturated ketones as nucleophilic/electrophilic acyl transfer reagents in the catalytic asymmetric reaction.Molecular diversity · 2026Review
- 4,5-Dihydro-2Molecules (Basel, Switzerland) · 2025Article
- Reactivity of δ-Functionalized Para-Quinone Methides in Nucleophilic Addition Reactions.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Facile Approach to Diverse Diarylmethane Scaffolds via DBU-Catalyzed 1,6-Addition Reaction: Discovery of an Antibacterial Agent.ACS omega · 2025Article
- Synthesis of fused-ring systems and diarylmethane flavonoidsRSC advances · 2025Article
- Asymmetric isochalcogenourea-catalysed (4 + 2)-cycloadditions ofOrganic & biomolecular chemistry · 2025Article
- Primary activation ofChemical science · 2024Article
- Chiral Lewis Base-Catalysed Asymmetric Syntheses of Benzo-fused ϵ-Lactones.European journal of organic chemistry · 2023Article
- One-Pot Synthesis of 3,4-Dihydrocoumarins via C-H Oxidation/Conjugate Addition/Cyclization Cascade Reaction.Molecules (Basel, Switzerland) · 2023Article
- Arylcyanomethylenequinone Oximes: An Overview of Synthesis, Chemical Transformations, and Biological Activity.Molecules (Basel, Switzerland) · 2023Review
- Isothiourea-Catalyzed Enantioselective Functionalisation of Glycine Schiff Base Aryl Esters via 1,6- and 1,4-Additions.ChemistryEurope · 2023Article
- Catalytic Access to 4-(sec-Alkyl)Anilines via 1,6-Conjugate Addition of Grignard Reagents toOrganic letters · 2022Article
- Organocatalytic Asymmetric [2 + 4] Cycloadditions of 3-Vinylindoles withMolecules (Basel, Switzerland) · 2021Article
- Isothiourea-Catalyzed Enantioselective α-Alkylation of Esters via 1,6-Conjugate Addition toMolecules (Basel, Switzerland) · 2021Article
- Diastereoselective synthesis of CFRSC advances · 2020Article
- Genetically Encoded Quinone Methides Enabling Rapid, Site-Specific, and Photocontrolled Protein Modification with Amine Reagents.Journal of the American Chemical Society · 2020Article
- Chiral Fe(ii) complex catalyzed enantioselective [1,3] O-to-C rearrangement of alkyl vinyl ethers and synthesis of chromanols and beyond.Chemical science · 2020Article
- One-pot synthesis of indoles and quinolinones fromRSC advances · 2020Article
- CFEuropean journal of organic chemistry · 2020Article
Corrections and comments
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Authors and funding
3 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Quinone methides (QMs) are highly reactive compounds that have been defined as "elusive" intermediates, or even as a "synthetic enigma" in organic chemistry. Indeed, there were just a handful of examples of their utilization in catalytic asymmetric settings until some years ago. This review collects organocatalytic asymmetric reactions that employ QMs as substrates and intermediates, from the early examples, mostly based on stabilized QMs bearing specific substitution patterns, to more recent contributions, which have dramatically expanded the scope of QM chemistry. In fact, it was only very recently that the generation of QMs in situ through strategies compatible with organocatalytic methodologies has been realized. This tactic has finally opened the gate to the full exploitation of these unstable intermediates, leading to a series of remarkable disclosures. Several types of synthetically powerful asymmetric addition and cycloaddition reactions, applicable to a broad range of QMs, are now available.
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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.