ArticleAngewandte Chemie (International ed. in English)2015
1,2-Azaborine: The Boron-Nitrogen Derivative of ortho-Benzyne.
Article in Angewandte Chemie (International ed. in English), 2015. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 11 papers.
What it found
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Who cites it
11 citing papers in PubMed.
- Understanding the Electronic Structure and Diels-Alder Reactivity of Nitrilium-TypeThe Journal of organic chemistry · 2026Article
- A Nitrilium-TypeJournal of the American Chemical Society · 2025Article
- COMPAS-4: A Data Set of (BN)Journal of chemical information and modeling · 2025Article
- Strain induced reactivity of cyclic iminoboranes: the (2 + 2) cycloaddition of a 1Chemical science · 2024Article
- Solution Phase Reactivity of Dibenzo[c,e][1,2]azaborinine: Activation and Insertion into Si-E Single Bonds (E=H, OSi(CHChemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- The Reaction of COAngewandte Chemie (International ed. in English) · 2021Article
- Ge=B π-Bonding: Synthesis and Reversible [2+2] Cycloaddition of Germaborenes.Angewandte Chemie (International ed. in English) · 2020Article
- Superelectrophilicity of 1,2-Azaborine: Formation of Xenon and Carbon Monoxide Adducts.Angewandte Chemie (International ed. in English) · 2019Article
- The Dewar Isomer of 1,2-Dihydro-1,2-azaborinines: Isolation, Fragmentation, and Energy Storage.Angewandte Chemie (International ed. in English) · 2018Article
- The State of the Art in Azaborine Chemistry: New Synthetic Methods and Applications.Journal of the American Chemical Society · 2018Review
- Reactivity of a coordinated inorganic acetylene unit, HBNH, and the azidoborane cation [HB(NChemical science · 2017Article
Corrections and comments
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Authors and funding
5 authors.
Funding
Abstract
The BN analogue of ortho-benzyne, 1,2-azaborine, is generated by flash vacuum pyrolysis, trapped under cryogenic conditions, and studied by direct spectroscopic techniques. The parent BN aryne spontaneously binds N2 and CO2, thus demonstrating its highly reactive nature. The interaction with N2 is photochemically reversible. The CO2 adduct of 1,2-azaborine is a cyclic carbamate which undergoes photocleavage, thus resulting in overall CO2 splitting.
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Registered trials
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