ArticleOrganic letters2015
Enantioselective Hydroformylation of 1-Alkenes with Commercial Ph-BPE Ligand.
Article in Organic letters, 2015. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
8 citing papers in PubMed.
- Computational tools for the prediction of site- and regioselectivity of organic reactions.Chemical science · 2025Review
- P(V)-Promoted Rh-Catalyzed Highly Regioselective Hydroformylation of Styrenes under Mild Conditions.Molecules (Basel, Switzerland) · 2024Article
- Substrate scope driven optimization of an encapsulated hydroformylation catalyst.Catalysis science & technology · 2024Article
- A substrate descriptor based approach for the prediction and understanding of the regioselectivity in caged catalyzed hydroformylation.Faraday discussions · 2023Article
- A Facile Approach to Bis(isoxazoles), Promising Ligands of the AMPA Receptor.Molecules (Basel, Switzerland) · 2021Article
- Recent Advances in the Synthesis of Ibuprofen and Naproxen.Molecules (Basel, Switzerland) · 2021Review
- Enantioselective Synthesis of 4-Methyl-3,4-dihydroisocoumarin via Asymmetric Hydroformylation of Styrene Derivatives.The Journal of organic chemistry · 2019Article
- Evolution of an Efficient and Scalable Nine-Step (Longest Linear Sequence) Synthesis of Zincophorin Methyl Ester.Journal of the American Chemical Society · 2017Article
Corrections and comments
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Authors and funding
4 authors.
Funding
Abstract
A rhodium complex, in conjunction with commercially available Ph-BPE ligand, catalyzes the branch-selective asymmetric hydroformylation of 1-alkenes and rapidly generates α-chiral aldehydes. A wide range of terminal olefins including 1-dodecene were examined, and all delivered high enantioselectivity (up to 98:2 er) as well as good branch:linear ratios (up to 15:1).
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Registered trials
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