ArticleJournal of the American Chemical Society2015
Modular Access to Substituted Azocanes via a Rhodium-Catalyzed Cycloaddition-Fragmentation Strategy.
Article in Journal of the American Chemical Society, 2015. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 20 papers.
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Who cites it
20 citing papers in PubMed, 94 citations in OpenAlex.
- Titanium cis-DACH Salan Catalyst for the Efficient Epoxidation of Nonactivated Olefins with Hydrogen Peroxide-Terminal-Selective Epoxidation of Multiply Unsaturated Terpenes.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Photo-induced intramolecular dearomative [5 + 4] cycloaddition of arenes for the construction of highly strained medium-sized-rings.Nature communications · 2024Article
- Zirconium and hafnium catalyzed C-C single bond hydroboration.Nature communications · 2024Article
- Stereoselective two-carbon ring expansion of allylic aminesChemical science · 2023Article
- An endo-Directing-Group Strategy Unlocks Enantioselective (3+1+2) Carbonylative Cycloadditions of Aminocyclopropanes.Angewandte Chemie (International ed. in English) · 2022Article
- Carbonylative N-Heterocyclization via Nitrogen-Directed C-C Bond Activation of Nonactivated Cyclopropanes.Journal of the American Chemical Society · 2022Article
- Diversity-Oriented Synthesis: Amino Acetophenones as Building Blocks for the Synthesis of Natural Product Analogs.Pharmaceuticals (Basel, Switzerland) · 2021Review
- Total Synthesis and Anti-Inflammatory Bioactivity of (-)-Majusculoic Acid and Its Derivatives.Marine drugs · 2021Article
- Synthesis of Benzo[b]azocin-2-ones by Aryl Amination and Ring-Expansion of α-(Iodophenyl)-β-oxoesters.Chemistry (Weinheim an der Bergstrasse, Germany) · 2019Article
- Stereoselective synthesis of medium lactams enabled by metal-free hydroalkoxylation/stereospecific [1,3]-rearrangement.Nature communications · 2019Article
- Copper-Catalyzed Chan-Lam Cyclopropylation of Phenols and Azaheterocycles.The Journal of organic chemistry · 2018Article
- Fused-Ring Formation by an Intramolecular "Cut-and-Sew" Reaction between Cyclobutanones and Alkynes.Angewandte Chemie (International ed. in English) · 2018Article
- Modular Access to Azepines by Directed Carbonylative C-C Bond Activation of Aminocyclopropanes.Journal of the American Chemical Society · 2018Article
- Rh-catalyzed regiodivergent hydrosilylation of acyl aminocyclopropanes controlled by monophosphine ligands.Chemical science · 2017Article
- Synthesis of Bridged Cyclopentane Derivatives by Catalytic Decarbonylative Cycloaddition of Cyclobutanones and Olefins.Angewandte Chemie (International ed. in English) · 2016Article
- New Initiation Modes for Directed Carbonylative C-C Bond Activation: Rhodium-Catalyzed (3 + 1 + 2) Cycloadditions of Aminomethylcyclopropanes.Journal of the American Chemical Society · 2016Article
- Synthesis and applications of rhodacyclopentanones derived from C-C bond activation.Chemical communications (Cambridge, England) · 2016Article
- Capture-Collapse Heterocyclization: 1,3-Diazepanes by C-N Reductive Elimination from Rhodacyclopentanones.Journal of the American Chemical Society · 2016Article
- Enantioselective Rh-Catalyzed Carboacylation of C═N Bonds via C-C Activation of Benzocyclobutenones.Journal of the American Chemical Society · 2016Article
- (4+1) vs (4+2): Catalytic Intramolecular Coupling between Cyclobutanones and Trisubstituted Allenes via C-C Activation.Journal of the American Chemical Society · 2015Article
Corrections and comments
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Authors and funding
4 authors at 3 institutions in 1 country.
Funding
Abstract
A short entry to substituted azocanes by a Rh-catalyzed cycloaddition-fragmentation process is described. Specifically, exposure of diverse N-cyclopropylacrylamides to phosphine-ligated cationic Rh(I) catalyst systems under a CO atmosphere enables the directed generation of rhodacyclopentanone intermediates. Subsequent insertion of the alkene component is followed by fragmentation to give the heterocyclic target. Stereochemical studies show, for the first time, that alkene insertion into rhodacyclopentanones can be reversible.
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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.