ArticleJournal of the American Chemical Society2015
A Nucleophilic Strategy for Enantioselective Intermolecular α-Amination: Access to Enantioenriched α-Arylamino Ketones.
Article in Journal of the American Chemical Society, 2015. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 13 papers.
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Who cites it
13 citing papers in PubMed.
- A Noncarbenoid Approach to Imidazolidines via ZnClThe Journal of organic chemistry · 2025Article
- Mechanochemical Thiolation of α-Imino Ketones: A Catalyst-Free, One-Pot, Three-Component Reaction.ACS omega · 2025Article
- Nickel-Catalyzed Enantioselective Decarboxylative Acylation: Rapid, Modular Access to α-Amino Ketones.Angewandte Chemie (International ed. in English) · 2023Article
- Molecular Editing of Pyrroles via a Skeletal Recasting Strategy.ACS central science · 2023Article
- Free Amino Group Transfer via α-Amination of Native Carbonyls.Angewandte Chemie (International ed. in English) · 2023Article
- Transfer freier Aminogruppen via α-Aminierung von Carbonylen.Angewandte Chemie (Weinheim an der Bergstrasse, Germany) · 2023Article
- Discovery of Novel Inhibitors of Uridine Diphosphate-Journal of medicinal chemistry · 2022Article
- Palladium-catalyzed benzylic C(spChemical science · 2021Article
- Light-Driven Carbene Catalysis for the Synthesis of Aliphatic and α-Amino Ketones.Angewandte Chemie (International ed. in English) · 2021Article
- Catalytic Asymmetric Formal [3+2] Cycloaddition of Azoalkenes with 3-Vinylindoles: Synthesis of 2,3-Dihydropyrroles.iScience · 2020Article
- Synthesis of γ-substituted carbonyl compounds from DMSO-mediated oxidation of enynamides: mechanistic insights and carbon- and hetero-functionalizations.Chemical science · 2019Article
- Direct catalytic enantioselective amination of ketones for the formation of tri- and tetrasubstituted stereocenters.Chemical science · 2018Article
- Chemo- and Stereoselective Transition-Metal-Free Amination of Amides with Azides.Journal of the American Chemical Society · 2016Article
Corrections and comments
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Authors and funding
3 authors.
Funding
Abstract
The enantioselective addition of anilines to azoalkenes was accomplished through the use of a chiral phosphoric acid catalyst. The resulting α-arylamino hydrazones were obtained in good yields and excellent enantioselectivities and provide access to enantioenriched α-arylamino ketones. A serendipitous kinetic resolution of racemic α-arylamino hydrazones is also described.
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Registered trials
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