Evidence map›Paper›PMID 26058560›Full record

ArticleAngewandte Chemie (International ed. in English)2015

Gadolinium-Catalyzed Regio- and Enantioselective Aminolysis of Aromatic trans-2,3-Epoxy Sulfonamides.

Chuan Wang, Hisashi Yamamoto

Abstract read
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2015. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Article
  2. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

2 authors.

Chuan WangDepartment of Chemistry, The University of Chicago, 5735 South Ellis Avenue, Chicago, IL 60637 (USA).
Hisashi YamamotoDepartment of Chemistry, The University of Chicago, 5735 South Ellis Avenue, Chicago, IL 60637 (USA). yamamoto@uchicago.edu, hyamamoto@jsc.chubu.ac.jp.

Funding

Catalytic Asymmetric Oxidation: Easy Entry to Highly Functionalized MoleculesR01GM068433 · NIGMS · UNIVERSITY OF CHICAGO · PI YAMAMOTO, HISASHI NONE · 2003 to 2014
$3.4M
NIGMS NIH HHS R01 GM068433PHS HHS 2R01M068433
6 · The paper itself

Abstract

The first enantioselective aminolysis of aromatic trans-2,3-epoxy sulfonamides has been accomplished, which was efficiently catalyzed by a Gd-N,N'-dioxide complex. Under the directing effect of the sulfonamide moiety the ring-opening reaction proceeded selectively at the C-3 position in a highly enantioselective manner furnishing various Ts- and SES-protected 3-amino-3-phenylpropan-2-olamines as products.

Indexed as

AminationAminesAmino AlcoholsEpoxy CompoundsGadoliniumHydrocarbons, AromaticStereoisomerismSulfonamidesAminesAmino AlcoholsEpoxy CompoundsGadoliniumHydrocarbons, AromaticSulfonamidesamino alcoholsgadolinium-catalysiskinetic resolutionregioselectivering opening

Identifiers

PMID26058560
PMCPMC4526255

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.