ReviewInterface focus2015
Artificial photosynthesis: understanding water splitting in nature.
Review in Interface focus, 2015. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 16 papers.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
16 citing papers in PubMed, 84 citations in OpenAlex.
- PathInHydro, a Set of Machine Learning Models to Identify Unbinding Pathways of Gas Molecules in [NiFe] Hydrogenases.Journal of chemical information and modeling · 2025Article
- Tracking the first electron transfer step at the donor side of oxygen-evolving photosystem II by time-resolved infrared spectroscopy.Photosynthesis research · 2024Article
- Characterization of the Bottlenecks and Pathways for Inhibitor Dissociation from [NiFe] Hydrogenase.Journal of chemical information and modeling · 2024Article
- Insights into PSII's SThe journal of physical chemistry letters · 2024Article
- Cluster size dependent coordination of formate to free manganese oxide clusters.Physical chemistry chemical physics : PCCP · 2023Article
- Bioinspired and Bioderived Aqueous Electrocatalysis.Chemical reviews · 2023Review
- Biocatalytic conversion of sunlight and carbon dioxide to solar fuels and chemicals.RSC advances · 2022Review
- From manganese oxidation to water oxidation: assembly and evolution of the water-splitting complex in photosystem II.Photosynthesis research · 2022Review
- Proton reduction by a bimetallic zinc selenolate electrocatalyst.RSC advances · 2022Article
- Article
- Article
- Light-driven catalysis with engineered enzymes and biomimetic systems.Biotechnology and applied biochemistry · 2020Review
- Water oxidation in photosystem II.Photosynthesis research · 2019Review
- Reactive Cobalt⁻Oxo Complexes of Tetrapyrrolic Macrocycles andMolecules (Basel, Switzerland) · 2018Review
- Manganese(II) complexes with Bn-tpen as powerful catalysts of cyclohexene oxidation.Chemicke zvesti · 2017Article
- Nano-sized Mn oxide/agglomerated silsesquioxane composite as a good catalyst for water oxidation.Photosynthesis research · 2016Article
Corrections and comments
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Authors and funding
4 authors at 2 institutions in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
In the context of a global artificial photosynthesis (GAP) project, we review our current work on nature's water splitting catalyst. In a recent report (Cox et al. 2014 Science 345, 804-808 (doi:10.1126/science.1254910)), we showed that the catalyst-a Mn4O5Ca cofactor-converts into an 'activated' form immediately prior to the O-O bond formation step. This activated state, which represents an all Mn(IV) complex, is similar to the structure observed by X-ray crystallography but requires the coordination of an additional water molecule. Such a structure locates two oxygens, both derived from water, in close proximity, which probably come together to form the product O2 molecule. We speculate that formation of the activated catalyst state requires inherent structural flexibility. These features represent new design criteria for the development of biomimetic and bioinspired model systems for water splitting catalysts using first-row transition metals with the aim of delivering globally deployable artificial photosynthesis technologies.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.