ArticleJournal of the American Chemical Society2015
Alkenyl carbonyl derivatives in enantioselective redox relay Heck reactions: accessing α,β-unsaturated systems.
Article in Journal of the American Chemical Society, 2015. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 33 papers.
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Who cites it
33 citing papers in PubMed.
- Palladium-catalyzed enantioselective alkenylation of acyclic alkenols: Broad scope with alkenyl bromides.Science advances · 2026Article
- Iridium-Catalyzed Enantioselective Vinylogous and Bisvinylogous Allenylic Substitution.JACS Au · 2024Article
- A substrate descriptor based approach for the prediction and understanding of the regioselectivity in caged catalyzed hydroformylation.Faraday discussions · 2023Article
- Regio- and enantioselective remote dioxygenation of internal alkenes.Nature chemistry · 2023Article
- γ-Selective C(spNature communications · 2021Article
- Selective Synthesis ofJournal of the American Chemical Society · 2021Article
- Rate Profiling the Impact of Remote Functional Groups on the Redox-Relay Heck Reaction.Organic letters · 2021Article
- Stereoselective Remote Functionalization via Palladium-Catalyzed Redox-Relay Heck Methodologies.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Review
- Transition State Force Field for the Asymmetric Redox-Relay Heck Reaction.Journal of the American Chemical Society · 2020Article
- Catalytic enantioselective synthesis of tetrasubstituted chromanonesChemical science · 2020Article
- Ni(I)-CatalyzedACS catalysis · 2019Article
- Nickel-catalyzed intermolecular oxidative Heck arylation driven by transfer hydrogenation.Nature communications · 2019Article
- Three-component vicinal-diarylation of alkenesChemical science · 2019Article
- Synthetic and Mechanistic Studies of a Versatile Heteroaryl Thioether Directing Group for Pd(II) Catalysis.ACS catalysis · 2019Article
- Palladium-catalyzed enantioselective alkenylation of alkenylbenzene derivatives.Chemical science · 2019Article
- Palladium-Catalyzed Enantioselective Alkenylation of Enelactams Using a Relay Heck Strategy.Chemistry (Weinheim an der Bergstrasse, Germany) · 2019Article
- Access to P-chiral phosphine oxides by enantioselective allylic alkylation of bisphenols.Chemical science · 2019Article
- Intermolecular Heck Coupling with Hindered Alkenes Directed by Potassium Carboxylates.Angewandte Chemie (International ed. in English) · 2019Article
- 11-Step Total Synthesis of Teleocidins B-1-B-4.Journal of the American Chemical Society · 2019Article
- Enantioselective C2-Alkylation of Indoles through a Redox-Relay Heck Reaction of 2-Indole Triflates.Chemistry (Weinheim an der Bergstrasse, Germany) · 2019Article
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4 authors.
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Abstract
A highly enantioselective and site-selective Pd-catalyzed arylation of alkenes linked to carbonyl derivatives to yield α,β-unsaturated systems is reported. The high site selectivity is attributed to both a solvent effect and the polarized nature of the carbonyl group, both of which have been analyzed through multidimensional analysis tools. The reaction can be performed in an iterative fashion allowing for a diastereoselective installation of two aryl groups along an alkyl chain.
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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.