ArticleScientific reports2015
Properties of water confined in ionic liquids.
Article in Scientific reports, 2015. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 12 papers.
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Who cites it
12 citing papers in PubMed.
- On the Moisture Absorption Capability of Ionic Liquids.The journal of physical chemistry. B · 2024Article
- Do Ionic Liquids Exhibit the Required Characteristics to Dissolve, Extract, Stabilize, and Purify Proteins? Past-Present-Future Assessment.Chemical reviews · 2024Review
- Interfacial Water and Microheterogeneity in Aqueous Solutions of Ionic Liquids.The journal of physical chemistry. B · 2022Article
- Influence of alkali metals on water dynamics inside imidazolium-based ionic liquid nano-domains.Frontiers in chemistry · 2022Article
- Structural Features of the [C4mim][Cl] Ionic Liquid and Its Mixtures with Water: Insight from aThe journal of physical chemistry. B · 2021Article
- Molecular insights on confined water in the nanochannels of self-assembled ionic liquid crystal.Science advances · 2021Article
- Revisiting Ionic Liquid Structure-Property Relationship: A Critical Analysis.International journal of molecular sciences · 2020Review
- Microstructural and Dynamical Heterogeneities in Ionic Liquids.Chemical reviews · 2020Article
- Tuning Water Networks via Ionic Liquid/Water Mixtures.International journal of molecular sciences · 2020Article
- Tailoring intermolecular interactions to develop a low-temperature electrolyte system consisting of 1-butyl-3-methylimidazolium iodide and organic solvents.RSC advances · 2019Article
- Utilizing Water Activity as a Simple Measure to Understand Hydrophobicity in Ionic Liquids.Frontiers in chemistry · 2019Article
- Two-State or Non-Two-State? An Excess Spectroscopy-based Approach to Differentiate the Existing Forms of Molecules in Liquids Mixtures.Scientific reports · 2015Article
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4 authors.
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Abstract
The varying states of water confined in the nano-domain structures of typical room temperature ionic liquids (ILs) were investigated by (1)H NMR and by measurements of self-diffusion coefficients while systematically varying the IL cations and anions. The NMR peaks for water in BF4-based ILs were clearly split, indicating the presence of two discrete states of confined water (H2O and HOD). Proton and/or deuterium exchange rate among the water molecules was very slowly in the water-pocket. Notably, no significant changes were observed in the chemical shifts of the ILs. Self-diffusion coefficient results showed that water molecules exhibit a similar degree of mobility, although their diffusion rate is one order of magnitude faster than that of the IL cations and anions. These findings provide information on a completely new type of confinement, that of liquid water in soft matter.
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