ArticleAngewandte Chemie (International ed. in English)2015
Reversible control of nanoparticle functionalization and physicochemical properties by dynamic covalent exchange.
Article in Angewandte Chemie (International ed. in English), 2015. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 17 papers.
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Who cites it
17 citing papers in PubMed.
- A Diborylcarbazolyl Ligand for Stabilizing Low-Coordinate and Low-Valent Metal Complexes.Inorganic chemistry · 2026Article
- Review
- Chemospecific Heterostructure and Heteromaterial Assembly of Metal-Organic Framework Nanoparticles.Journal of the American Chemical Society · 2025Article
- Supramolecular Click Chemistry for Surface Modification of Quantum Dots Mediated by Cucurbit[7]uril.ACS nano · 2023Article
- A General One-Step Synthesis of Alkanethiyl-Stabilized Gold Nanoparticles with Control over Core Size and Monolayer Functionality.Chemistry of materials : a publication of the American Chemical Society · 2023Article
- Constitutionally Selective Dynamic Covalent Nanoparticle Assembly.Journal of the American Chemical Society · 2022Article
- Rapidly Adaptive All-covalent Nanoparticle Surface Engineering.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Regulating the reactivity of black phosphorus via protective chemistry.Science advances · 2020Article
- Template effects of vesicles in dynamic covalent chemistry.Chemical science · 2020Article
- Programmable dynamic covalent nanoparticle building blocks with complementary reactivity.Chemical science · 2020Article
- Synthesis and Structure-Activity Relationship Study of Antimicrobial Auranofin against ESKAPE Pathogens.Journal of medicinal chemistry · 2019Article
- Continuum tuning of nanoparticle interfacial properties by dynamic covalent exchange.Chemical science · 2018Article
- Structural Characterization of Biofunctionalized Gold Nanoparticles by Ultrahigh-Resolution Mass Spectrometry.ACS nano · 2017Article
- Oximes and Hydrazones in Bioconjugation: Mechanism and Catalysis.Chemical reviews · 2017Review
- Article
- Antiparallel Dynamic Covalent Chemistries.Journal of the American Chemical Society · 2017Article
- Dynamic Covalent Nanoparticle Building Blocks.Chemistry (Weinheim an der Bergstrasse, Germany) · 2016Article
Corrections and comments
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Authors and funding
2 authors.
Funding
Abstract
Existing methods for the covalent functionalization of nanoparticles rely on kinetically controlled reactions, and largely lack the sophistication of the preeminent oligonucleotide-based noncovalent strategies. Here we report the application of dynamic covalent chemistry for the reversible modification of nanoparticle (NP) surface functionality, combining the benefits of non-biomolecular covalent chemistry with the favorable features of equilibrium processes. A homogeneous monolayer of nanoparticle-bound hydrazones can undergo quantitative dynamic covalent exchange. The pseudomolecular nature of the NP system allows for the in situ characterization of surface-bound species, and real-time tracking of the exchange reactions. Furthermore, dynamic covalent exchange offers a simple approach for reversibly switching—and subtly tuning—NP properties such as solvophilicity.
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