Evidence map›Paper›PMID 25960366›Full record

ArticleAngewandte Chemie (International ed. in English)2015

A Solomon link through an interwoven molecular grid.

Jonathon E Beves, Jonathan J Danon, David A Leigh, Jean-François Lemonnier, Iñigo J Vitorica-Yrezabal

Abstract read
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2015. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 27 papers.

0numbers the graph read from it
0cells of the map it votes in
27citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

27 citing papers in PubMed.

  1. Design and Structural Transformations of Zinc(II) Knotted Cage Frameworks.Angewandte Chemie (International ed. in English) · 2025
    Article
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  5. The End of the Beginning of Mechanical Stereochemistry.Accounts of chemical research · 2024
    Article
  6. The Final Stereogenic Unit of [2]Rotaxanes: Type 2 Geometric Isomers.Journal of the American Chemical Society · 2024
    Article
  7. Article
  8. Review
  9. Article
  10. Review
  11. Molecular weaving.Nature materials · 2022
    Review
  12. A molecular endless (7Nature chemistry · 2021
    Article
  13. Article
  14. Stereoselective Synthesis of Molecular Square and Granny Knots.Journal of the American Chemical Society · 2019
    Article
  15. Coordination Chemistry of a Molecular Pentafoil Knot.Journal of the American Chemical Society · 2019
    Article
  16. Stereoselective Synthesis of Mechanically Planar Chiral Rotaxanes.Angewandte Chemie (International ed. in English) · 2018
    Article
  17. Article
  18. Article
  19. Article
  20. Chirality in rotaxanes and catenanes.Chemical Society reviews · 2018
    Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors.

Jonathon E BevesSchool of Chemistry, University of Edinburgh, The King's Buildings, West Mains Road, Edinburgh, EH9 3JJ (UK).
Jonathan J DanonSchool of Chemistry, University of Manchester, Oxford Road, Manchester, M13 9PL (UK) http://www.catenane.net.
David A LeighSchool of Chemistry, University of Edinburgh, The King's Buildings, West Mains Road, Edinburgh, EH9 3JJ (UK). David.Leigh@manchester.ac.uk.
Jean-François LemonnierSchool of Chemistry, University of Manchester, Oxford Road, Manchester, M13 9PL (UK) http://www.catenane.net.
Iñigo J Vitorica-YrezabalSchool of Chemistry, University of Manchester, Oxford Road, Manchester, M13 9PL (UK) http://www.catenane.net.

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

A molecular Solomon link was synthesized through the assembly of an interwoven molecular grid consisting of four bis(benzimidazolepyridyl)benzthiazolo[5,4-d]thiazole ligands and four zinc(II), iron(II), or cobalt(II) cations, followed by ring-closing olefin metathesis. NMR spectroscopy, mass spectrometry, and X-ray crystallography confirmed the doubly interlocked topology, and subsequent demetalation afforded the wholly organic Solomon link. The synthesis, in which each metal ion defines the crossing point of two ligand strands, suggests that interwoven molecular grids should be useful scaffolds for the rational construction of other topologically complex structures.

Indexed as

catenanescoordination chemistrymolecular gridsself-assemblysupramolecular chemistry

Identifiers

PMID25960366
PMCPMC4479027

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.