ArticleEuropean polymer journal2015
Accessing photo-based morphological control in phase-separated, cross-linked networks through delayed gelation.
Article in European polymer journal, 2015. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
4 citing papers in PubMed, 25 citations in OpenAlex.
- Photopolymerization-Induced Phase Separation in a Polypropylene Glycol-Modified Dimethacrylate System.Polymers · 2026Article
- Effect of Block Copolymer Self-Assembly on Phase Separation in Photopolymerizable Epoxy Blends.Macromolecules · 2024Article
- From Unregulated Networks to Designed Microstructures: Introducing Heterogeneity at Different Length Scales in Photopolymers for Additive Manufacturing.Chemical reviews · 2024Review
- Article
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Authors and funding
2 authors at 2 institutions in 1 country.
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Abstract
This work presents an approach to extend the period for phase separation, independent of temperature, in ambient phase-separating photopolymerizations based on the copolymerization of structurally similar mono- and di-vinyl monomers. Copolymer resins composed of triethylene glycol dimethacrylate (TEGDMA) and ethylene glycol methyl ether methacrylate (EGMEMA) were modified with a thermoplastic prepolymer, poly(butyl methacrylate). With increasing EGMEMA modification into the bulk TEGDMA resin, there is a decrease in the initial reaction rate, which increases the time for development of compositionally different phases prior to network gelation. The period between phase separation and gelation was probed through optical and rheological measurements, and it was extended from 22 s in a TEGDMA resin to 69 s in a TEGDMA:EGMEMA copolymer, allowing these materials to be processed under a wide range of UV-irradiation intensities (300 µW cm
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Registered trials
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