ArticleJournal of the American Chemical Society2015
Influence of backbone conformational rigidity in temperature-sensitive amphiphilic supramolecular assemblies.
Article in Journal of the American Chemical Society, 2015. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
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Who cites it
8 citing papers in PubMed.
- Thermosensitive core-rigid micelles of monomethoxy poly(ethylene glycol)-deoxy cholic acid.Biomaterials research · 2022Article
- Controlling Liquid Crystal Configuration and Phase Using Multiple Molecular Triggers.Molecules (Basel, Switzerland) · 2022Article
- Molecular bases for temperature sensitivity in supramolecular assemblies and their applications as thermoresponsive soft materials.Materials horizons · 2022Review
- Cooperatively assembled liquid crystals enable temperature-controlled Förster resonance energy transfer.Chemical science · 2021Article
- A New Strategy for Reporting Specific Protein Binding Events at Aqueous-Liquid Crystal Interfaces in the Presence of Non-Specific Proteins.ACS applied materials & interfaces · 2020Article
- Insights into the Kinetics of Supramolecular Comonomer Incorporation in Water.Macromolecules · 2019Article
- Perylene bisimide hydrogels and lyotropic liquid crystals with temperature-responsive color change.Chemical science · 2016Article
- Role of Aromatic Interactions in Temperature-Sensitive Amphiphilic Supramolecular Assemblies.Langmuir : the ACS journal of surfaces and colloids · 2016Article
Corrections and comments
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Authors and funding
5 authors.
Funding
Abstract
Molecular design features that endow amphiphilic supramolecular assemblies with a unique temperature-sensitive transition have been investigated. We find that conformational rigidity in the backbone is an important feature for eliciting this feature. We also find that intramolecular hydrogen-bonding can induce such rigidity in amphiphile backbone. Guest encapsulation stability of these assemblies was found to be significantly altered within a narrow temperature window, which correlates with the temperature-sensitive size transition of the molecular assembly. Molecular design principles demonstrated here could have broad implications in developing future temperature-responsive systems.
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Registered trials
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