ArticleChemical physics letters2013
Radical re-appraisal of water structure in hydrophilic confinement.
Article in Chemical physics letters, 2013. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.
What it found
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Who cites it
10 citing papers in PubMed.
- Probing the Behaviour of Fluids Confined in Porous Materials by Neutron Scattering: Applications to COChemPlusChem · 2024Review
- Complexity of confined water vitrification and its glass transition temperature.Proceedings of the National Academy of Sciences of the United States of America · 2024Article
- Walking on water: revisiting the role of water in articular cartilage biomechanics in relation to tissue engineering and regenerative medicine.Journal of the Royal Society, Interface · 2022Review
- Ordered Mesoporous Silica Prepared in Different Solvent Conditions: Application for Cu(II) and Pb(II) Adsorption.Gels (Basel, Switzerland) · 2022Article
- Consequences of Convex Nanopore Chemistry on Confined Water Dynamics.The journal of physical chemistry. B · 2020Article
- Specific Heat and Transport Functions ofWater.International journal of molecular sciences · 2020Article
- Confinement Effects on the Benzene Orientational Structure.Angewandte Chemie (International ed. in English) · 2018Article
- Highly compressed water structure observed in a perchlorate aqueous solution.Nature communications · 2017Article
- Water: A Tale of Two Liquids.Chemical reviews · 2016Article
- Segregated water observed in a putative fish embryo cryopreservative.Royal Society open science · 2016Article
Corrections and comments
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Authors and funding
1 author.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The structure of water confined in MCM41 silica cylindrical pores is studied to determine whether confined water is simply a version of the bulk liquid which can be substantially supercooled without crystallisation. A combination of total neutron scattering from the porous silica, both wet and dry, and computer simulation using a realistic model of the scattering substrate is used. The water in the pore is divided into three regions: core, interfacial and overlap. The average local densities of water in these simulations are found to be about 20% lower than bulk water density, while the density in the core region is below, but closer to, the bulk density. There is a decrease in both local and core densities when the temperature is lowered from 298 K to 210 K. The radical proposal is made here that water in hydrophilic confinement is under significant tension, around -100 MPa, inside the pore.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.