ArticleJournal of the American Chemical Society2015
Light-driven, proton-controlled, catalytic aerobic C-H oxidation mediated by a Mn(III) porphyrinoid complex.
Article in Journal of the American Chemical Society, 2015. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 16 papers.
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Who cites it
16 citing papers in PubMed.
- Ultra-thin g-CMaterials advances · 2021Article
- Oxidative Cleavage of Alkenes by OJournal of the American Chemical Society · 2021Article
- Benzylic C-H acylation by cooperative NHC and photoredox catalysis.Nature communications · 2021Article
- Copper-Catalyzed Vinylogous Aerobic Oxidation of Unsaturated Compounds with Air.Journal of the American Chemical Society · 2018Article
- A Reactive Manganese(IV)-Hydroxide Complex: A Missing Intermediate in Hydrogen Atom Transfer by High-Valent Metal-Oxo Porphyrinoid Compounds.Journal of the American Chemical Society · 2018Article
- Incorporation of redox-inactive cations promotes iron catalyzed aerobic C-H oxidation at mild potentials.Chemical science · 2018Article
- Dioxygen Activation and O-O Bond Formation Reactions by Manganese Corroles.Journal of the American Chemical Society · 2017Article
- meso-N-Methylation of a porphyrinoid complex: activating the H-atom transfer capability of an inert ReChemical communications (Cambridge, England) · 2017Article
- High-Valent Manganese-Oxo Valence Tautomers and the Influence of Lewis/Brönsted Acids on C-H Bond Cleavage.Inorganic chemistry · 2016Article
- Activation of Dioxygen by Iron and Manganese Complexes: A Heme and Nonheme Perspective.Journal of the American Chemical Society · 2016Review
- The Influence of Peripheral Substituent Modification on P(V), Mn(III), and Mn(V)(O) Corrolazines: X-ray Crystallography, Electrochemical and Spectroscopic Properties, and HAT and OAT Reactivities.Inorganic chemistry · 2016Article
- Proton-Coupled Electron Transfer in Organic Synthesis: Fundamentals, Applications, and Opportunities.Topics in current chemistry (Cham) · 2016Review
- Photocatalytic Oxygenation of Substrates by Dioxygen with Protonated Manganese(III) Corrolazine.Inorganic chemistry · 2016Article
- Rhenium(V)-oxo corrolazines: isolating redox-active ligand reactivity.Chemical communications (Cambridge, England) · 2016Article
- A Balancing Act: Stability versus Reactivity of Mn(O) Complexes.Accounts of chemical research · 2015Article
- Strong Inhibition of O-Atom Transfer Reactivity for Mn(IV)(O)(π-Radical-Cation)(Lewis Acid) versus Mn(V)(O) Porphyrinoid Complexes.Journal of the American Chemical Society · 2015Article
Corrections and comments
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Authors and funding
7 authors.
Funding
Abstract
The visible light-driven, catalytic aerobic oxidation of benzylic C-H bonds was mediated by a Mn(III) corrolazine complex. To achieve catalytic turnovers, a strict selective requirement for the addition of protons was established. The resting state of the catalyst was unambiguously characterized by X-ray diffraction as [Mn(III)(H2O)(TBP8Cz(H))](+), in which a single, remote site on the ligand is protonated. If two remote sites are protonated, however, reactivity with O2 is shut down. Spectroscopic methods revealed that the related Mn(V)(O) complex is also protonated at the same remote site at -60 °C, but undergoes valence tautomerization upon warming.
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