Evidence map›Paper›PMID 25803313›Full record

ArticleOrganic letters2015

Chemoselective formation of unsymmetrically substituted ethers from catalytic reductive coupling of aldehydes and ketones with alcohols in aqueous solution.

Nishantha Kalutharage, Chae S Yi

Abstract read
In one paragraph

Article in Organic letters, 2015. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

  1. Review
  2. Article
  3. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

2 authors.

Nishantha KalutharageDepartment of Chemistry, Marquette University, Milwaukee, Wisconsin 53201-1881 United States.
Chae S YiDepartment of Chemistry, Marquette University, Milwaukee, Wisconsin 53201-1881 United States.

Funding

Catalytic Coupling Reactions via C-H and C-N Bond ActivationR15GM109273 · NIGMS · MARQUETTE UNIVERSITY · PI YI, CHAE S · 2014 to 2014
$334k
NIGMS NIH HHS R15 GM109273
6 · The paper itself

Abstract

A well-defined cationic Ru-H complex catalyzes reductive etherification of aldehydes and ketones with alcohols. The catalytic method employs environmentally benign water as the solvent and cheaply available molecular hydrogen as the reducing agent to afford unsymmetrical ethers in a highly chemoselective manner.

Indexed as

AlcoholsAldehydesCatalysisEthersKetonesMolecular StructureOxidation-ReductionRhodiumStereoisomerismAlcoholsAldehydesEthersKetonesRhodium

Identifiers

PMID25803313
PMCPMC6585420

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.