Evidence map›Paper›PMID 25797002›Full record

ReviewJournal of magnetic resonance (San Diego, Calif. : 1997)2015

Mechanisms of dynamic nuclear polarization in insulating solids.

T V Can, Q Z Ni, R G Griffin

Abstract readReview
In one paragraph

Review in Journal of magnetic resonance (San Diego, Calif. : 1997), 2015. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 60 papers.

0numbers the graph read from it
0cells of the map it votes in
60citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

60 citing papers in PubMed.

  1. Article
  2. Overhauser Dynamic Nuclear Polarization of Lithiated Graphite Anodes: Probing Bulk and Surface Structures.Chemistry of materials : a publication of the American Chemical Society · 2025
    Article
  3. Stability of the polarization agent AsymPolPOK in intact and lysed mammalian cells.Journal of magnetic resonance (San Diego, Calif. : 1997) · 2025
    Article
  4. Review
  5. Review
  6. Article
  7. Article
  8. Article
  9. Cryogenic and Dissolution DNP NMR on γ-Irradiated Organic Molecules.Journal of the American Chemical Society · 2024
    Article
  10. Article
  11. Article
  12. Article
  13. Resonant Mixing Dynamic Nuclear Polarization.The journal of physical chemistry letters · 2023
    Article
  14. Review
  15. Frontiers in the Application of RF Vacuum Electronics.IEEE transactions on electron devices · 2023
    Article
  16. Coherent Dynamic Nuclear Polarization using Chirped Pulses.The journal of physical chemistry letters · 2023
    Article
  17. Article
  18. Review
  19. Article
  20. Biradical Polarizing Agents at High Fields.The journal of physical chemistry. B · 2022
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

3 authors.

T V CanFrancis Bitter Magnet Laboratory and Department of Chemistry, Massachusetts Institute of Technology, Cambridge, MA 02139, United States.
Q Z NiFrancis Bitter Magnet Laboratory and Department of Chemistry, Massachusetts Institute of Technology, Cambridge, MA 02139, United States.
R G GriffinFrancis Bitter Magnet Laboratory and Department of Chemistry, Massachusetts Institute of Technology, Cambridge, MA 02139, United States.

Funding

OverallP41EB002026 · NIBIB · MASSACHUSETTS INSTITUTE OF TECHNOLOGY · PI GRIFFIN, ROBERT GUY · 2003 to 2018
$17.9M
High Field DNP in Biological SystemsR01EB002804 · NIBIB · MASSACHUSETTS INSTITUTE OF TECHNOLOGY · PI GRIFFIN, ROBERT GUY · 2003 to 2018
$9.1M
Solid State NMR Studies of Peptides and ProteinsR01EB003151 · NIBIB · MASSACHUSETTS INSTITUTE OF TECHNOLOGY · PI GRIFFIN, ROBERT GUY · 2004 to 2015
$6.5M
Solid State NMR Studies of Membrane ProteinsR01EB001960 · NIBIB · MASSACHUSETTS INSTITUTE OF TECHNOLOGY · PI GRIFFIN, ROBERT GUY · 2003 to 2017
$6.5M
Console for an 800/89 DNP SpectrometerS10OD012023 · OD · MASSACHUSETTS INSTITUTE OF TECHNOLOGY · PI GRIFFIN, ROBERT GUY · 2013 to 2013
$539k
800 MHz Low Temperature Magic Angle Spinning NMR Probe.S10RR027895 · NCRR · MASSACHUSETTS INSTITUTE OF TECHNOLOGY · PI GRIFFIN, ROBERT GUY · 2009 to 2009
$300k
NCRR NIH HHS S10 RR027895NIBIB NIH HHS EB-001960NIBIB NIH HHS EB-002026NIBIB NIH HHS EB-002804NIBIB NIH HHS EB-003151NIBIB NIH HHS P41 EB002026NIBIB NIH HHS R01 EB001960NIBIB NIH HHS R01 EB002804NIBIB NIH HHS R01 EB003151NIH HHS S10 OD012023
6 · The paper itself

Abstract

Dynamic nuclear polarization (DNP) is a technique used to enhance signal intensities in NMR experiments by transferring the high polarization of electrons to their surrounding nuclei. The past decade has witnessed a renaissance in the development of DNP, especially at high magnetic fields, and its application in several areas including biophysics, chemistry, structural biology and materials science. Recent technical and theoretical advances have expanded our understanding of established experiments: for example, the cross effect DNP in samples spinning at the magic angle. Furthermore, new experiments suggest that our understanding of the Overhauser effect and its applicability to insulating solids needs to be re-examined. In this article, we summarize important results of the past few years and provide quantum mechanical explanations underlying these results. We also discuss future directions of DNP and current limitations, including the problem of resolution in protein spectra recorded at 80-100 K.

Indexed as

AlgorithmsModels, ChemicalElectric ConductivityNuclear Magnetic Resonance, BiomolecularProteinsProteinsCross effectDynamic nuclear polarization (DNP)Overhauser effectProtein NMRPulsed DNP

Identifiers

PMID25797002
PMCPMC4371145

What OpenQuestion holds

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Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.