ArticleChemistry (Weinheim an der Bergstrasse, Germany)2015
Gold carbene or carbenoid: is there a difference?
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2015. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 35 papers.
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Who cites it
35 citing papers in PubMed, 291 citations in OpenAlex.
- Catalytic Methods for the Transfer of Nonstabilized Carbenes.ACS catalysis · 2026Review
- Gold-Catalyzed Reactions between 2-Alkenyl-1-arylalkynes and Nitrones via 1,2-C,N-Difunctionalizations Together with the C═C Double Bond Cleavage.The Journal of organic chemistry · 2025Article
- Difluoro Carbenes: From Genuine Gold Complexes to Unprecedented Metallacyclic Reactivity.Angewandte Chemie (International ed. in English) · 2025Article
- Self-Assembly of a Customizable Library of Nickel Trifluoromethylation Catalysts via Selective C─F and C─O Bond Cleavage.Angewandte Chemie (International ed. in English) · 2025Article
- Insertion of Nitriles Into a Gold(III)/Carbene Bond: A Direct and Powerful Entry to Imino-Substituted Carbenes.Angewandte Chemie (International ed. in English) · 2025Article
- Exploring the capabilities of 2-alkynyl aryl/benzyl azides: synthesis approaches for indoles, quinolines, and their derivativesRSC advances · 2025Review
- Ag(I)-Catalyzed Oxidative Cyclization of 1,4-Diynamide-3-ols with N-Oxide for Divergent Synthesis of 2-Substituted Furan-4-carboxamide Derivatives.The Journal of organic chemistry · 2024Article
- Review
- 1,2-Silyl Rearrangement in Gold Carbene Chemistry: Synthesis of Furyl-Decorated Tetrasubstituted Silylallene Derivatives.Organic letters · 2024Article
- Gold-Catalyzed Cyclization of Yndiamides with Isoxazoles via α-Imino Gold Fischer Carbenes.Chemistry (Weinheim an der Bergstrasse, Germany) · 2023Article
- Gold(I) Catalysis Applied to the Stereoselective Synthesis of Indeno[2,1-Organic letters · 2022Article
- Gold(I) α-Trifluoromethyl Carbenes: Synthesis, Characterization and Reactivity Studies.Angewandte Chemie (International ed. in English) · 2022Article
- Selective Functionalization of Arene C(spACS catalysis · 2022Article
- Boosting Gold(I) Catalysis via Weak Interactions: New Fine-Tunable Impy Ligands.ACS organic & inorganic Au · 2022Article
- Dichotomy of platinum(II) and gold(III) carbene intermediates switching from N- to O-selectivity.Nature communications · 2022Article
- Gold-Catalyzed Reaction of Propargyl Esters and Alkynylsilanes: Synthesis of Vinylallene Derivatives through a Twofold 1,2-Rearrangement.Angewandte Chemie (International ed. in English) · 2021Article
- Gold-Catalyzed Synthesis of Small Rings.Chemical reviews · 2021Article
- Homogeneous Gold-Catalyzed Oxidation Reactions.Chemical reviews · 2021Review
- Gold(I)-catalyzed intramolecular cyclization/intermolecular cycloaddition cascade as a fast track to polycarbocycles and mechanistic insights.Nature communications · 2021Article
- On the Structure of Intermediates in Enyne Gold(I)-Catalyzed Cyclizations: Formation of trans-Fused Bicyclo[5.1.0]octanes as a Case Study.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
Corrections and comments
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Authors and funding
3 authors at 1 institution in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
By reviewing the recent progress on the elucidation of the structure of gold carbenes and the definitions of metal carbenes and carbenoids, we recommend to use the term gold carbene to describe gold carbene-like intermediates, regardless of whether the carbene or carbocation extreme resonance dominates. Gold carbenes, because of the weak metal-to-carbene π-back-donation and their strongly electrophilic reactivity, could be classified into the broader family of Fischer carbenes, although their behavior and properties are very specific.
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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.