ArticleNature communications2015
Exploitation of desilylation chemistry in tailor-made functionalization on diverse surfaces.
Article in Nature communications, 2015. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
5 citing papers in PubMed.
- Ballistic Conductance through Porphyrin Nanoribbons.Journal of the American Chemical Society · 2024Article
- Signatures of Room-Temperature Quantum Interference in Molecular Junctions.Accounts of chemical research · 2023Article
- Multi-component self-assembled molecular-electronic films: towards new high-performance thermoelectric systems.Chemical science · 2022Article
- Article
- An electrochemical aptasensor for amyloid-β oligomer based on double-stranded DNA as "conductive spring".Mikrochimica acta · 2020Article
Corrections and comments
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Authors and funding
11 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Interface engineering to attain a uniform and compact self-assembled monolayer at atomically flat surfaces plays a crucial role in the bottom-up fabrication of organic molecular devices. Here we report a promising and operationally simple approach for modification/functionalization not only at ultraflat single-crystal metal surfaces, M(111) (M=Au, Pt, Pd, Rh and Ir) but also at the highly oriented pyrolytic graphite surface, upon efficient in situ cleavage of trimethylsilyl end groups of the molecules. The obtained self-assembled monolayers are ultrastable within a wide potential window. The carbon-surface bonding on various substrates is confirmed by shell-isolated nanoparticle-enhanced Raman spectroscopy. Application of this strategy in tuning surface wettability is also demonstrated. The most valuable finding is that a combination of the desilylation with the click chemistry represents an efficient method for covalent and tailor-made functionalization of diverse surfaces.
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Registered trials
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