ArticleJournal of the American Chemical Society2015
Spectroscopic identification of an Fe(III) center, not Fe(IV), in the crystalline Sc-O-Fe adduct derived from [Fe(IV)(O)(TMC)]²⁺.
Article in Journal of the American Chemical Society, 2015. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 16 papers.
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16 citing papers in PubMed.
- Activation of the Ground and Excited State of a Luminescent Osmium(VI) Dioxo Dicyano Complex with Lewis Acids.Journal of the American Chemical Society · 2026Article
- High-Valent Late Transition Metal-Oxo Complexes: Breaking Boundaries at the Oxo Wall and Beyond.Chemical reviews · 2026Review
- When theory came first: a review of theoretical chemical predictions ahead of experiments.Pure and applied chemistry. Chimie pure et appliquee · 2025Review
- Redox Processes Involving Oxygen: The Surprising Influence of Redox-Inactive Lewis Acids.JACS Au · 2024Review
- Rapid Iron(III)-Fluoride-Mediated Hydrogen Atom Transfer.Angewandte Chemie (International ed. in English) · 2021Article
- C-H Bond Cleavage by Bioinspired Nonheme Metal Complexes.Inorganic chemistry · 2021Review
- Iron and manganese oxo complexes, oxo wall and beyond.Nature reviews. Chemistry · 2020Review
- Effects of Noncovalent Interactions on High-Spin Fe(IV)-Oxido Complexes.Journal of the American Chemical Society · 2020Article
- Lewis versus Brønsted Acid Activation of a Mn(IV) Catalyst for Alkene Oxidation.Inorganic chemistry · 2019Article
- Effects of Lewis Acidic Metal Ions (M) on Oxygen-Atom Transfer Reactivity of Heterometallic MnInorganic chemistry · 2019Article
- Oxoiron(IV) complexes as synthons for the assembly of heterobimetallic centers such as the Fe/Mn active site of Class Ic ribonucleotide reductases.Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry · 2018Article
- Characterization of the Fleeting Hydroxoiron(III) Complex of the Pentadentate TMC-py Ligand.Inorganic chemistry · 2017Article
- Facile and Reversible Formation of Iron(III)-Oxo-Cerium(IV) Adducts from Nonheme Oxoiron(IV) Complexes and Cerium(III).Angewandte Chemie (International ed. in English) · 2017Article
- The Two Faces of Tetramethylcyclam in Iron Chemistry: Distinct Fe-O-M Complexes Derived from [FeInorganic chemistry · 2017Article
- Mono- and binuclear non-heme iron chemistry from a theoretical perspective.Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry · 2016Review
- Characterization of a heterobimetallic nonheme Fe(III)-O-Cr(III) species formed by O2 activation.Chemical communications (Cambridge, England) · 2015Article
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Abstract
The apparent Sc(3+) adduct of [Fe(IV)(O)(TMC)](2+) (1, TMC = 1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane) has been synthesized in amounts sufficient to allow its characterization by various spectroscopic techniques. Contrary to the earlier assignment of a +4 oxidation state for the iron center of 1, we establish that 1 has a high-spin iron(III) center based on its Mössbauer and EPR spectra and its quantitative reduction by 1 equiv of ferrocene to [Fe(II)(TMC)](2+). Thus, 1 is best described as a Sc(III)-O-Fe(III) complex, in agreement with previous DFT calculations (Swart, M. Chem. Commun. 2013, 49, 6650.). These results shed light on the interaction of Lewis acids with high-valent metal-oxo species.
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