ArticleNature communications2015
Visualizing the non-equilibrium dynamics of photoinduced intramolecular electron transfer with femtosecond X-ray pulses.
Article in Nature communications, 2015. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 57 papers.
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Who cites it
57 citing papers in PubMed, 164 citations in OpenAlex.
- Article
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- Ultrafast metal-to-ligand electron transfer driven by bond shortening revealed through dual-edge computational X-ray spectroscopy.Communications chemistry · 2026Article
- Evaluating bioassay efficacy of extremophile bacillus species for environmentally safe control of Aedes aegypti larvae.Scientific reports · 2025Article
- Ultrafast charge-transfer-induced spin transition in cobalt-tungstate molecular photomagnets.Nature communications · 2025Article
- A high-energy Laue X-ray emission spectrometer at the FXE instrument at the European XFEL.Journal of synchrotron radiation · 2025Article
- Mixed gain detector configurations for time-resolved X-ray solution scattering.Journal of synchrotron radiation · 2025Article
- Ultrafast Two-Color X-Ray Emission Spectroscopy Reveals Excited State Landscape in a Base Metal Dyad.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- Real-time structural dynamics of the ultrafast solvation process around photo-excited aqueous halides.Chemical science · 2024Article
- Development of the multiplex imaging chamber at PAL-XFEL.Journal of synchrotron radiation · 2024Article
- A comparative review of time-resolved x-ray and electron scattering to probe structural dynamics.Structural dynamics (Melville, N.Y.) · 2024Review
- Cerium Photocatalyst in Action: Structural Dynamics in the Presence of Substrate Visualized via Time-Resolved X-ray Liquidography.Journal of the American Chemical Society · 2023Article
- Experimental capabilities for liquid jet samples at sub-MHz rates at the FXE Instrument at European XFEL.Journal of synchrotron radiation · 2023Article
- Ultrafast Jahn-Teller Photoswitching in Cobalt Single-Ion Magnets.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2023Article
- A theoretical study of the time-resolved x-ray absorption spectrum of the photoionized BT-1T cation.Structural dynamics (Melville, N.Y.) · 2023Article
- Sensitivity of Kβ mainline X-ray emission to structural dynamics in iron photosensitizer.Physical chemistry chemical physics : PCCP · 2023Article
- Atomic-scale observation of solvent reorganization influencing photoinduced structural dynamics in a copper complex photosensitizer.Chemical science · 2023Article
- Reaction dynamics studiedChemical science · 2022Review
- Hole Dynamics in Photoexcited Hematite Studied with Femtosecond Oxygen K-edge X-ray Absorption Spectroscopy.The journal of physical chemistry letters · 2022Article
- 3D printed devices and infrastructure for liquid sample delivery at the European XFEL.Journal of synchrotron radiation · 2022Article
Corrections and comments
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Authors and funding
32 authors at 13 institutions in 8 countries.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Ultrafast photoinduced electron transfer preceding energy equilibration still poses many experimental and conceptual challenges to the optimization of photoconversion since an atomic-scale description has so far been beyond reach. Here we combine femtosecond transient optical absorption spectroscopy with ultrafast X-ray emission spectroscopy and diffuse X-ray scattering at the SACLA facility to track the non-equilibrated electronic and structural dynamics within a bimetallic donor-acceptor complex that contains an optically dark centre. Exploiting the 100-fold increase in temporal resolution as compared with storage ring facilities, these measurements constitute the first X-ray-based visualization of a non-equilibrated intramolecular electron transfer process over large interatomic distances. Experimental and theoretical results establish that mediation through electronically excited molecular states is a key mechanistic feature. The present study demonstrates the extensive potential of femtosecond X-ray techniques as diagnostics of non-adiabatic electron transfer processes in synthetic and biological systems, and some directions for future studies, are outlined.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.