ArticleChemistry (Weinheim an der Bergstrasse, Germany)2015
Ru-catalysed C-H arylation of indoles and pyrroles with boronic acids: scope and mechanistic studies.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2015. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 13 papers.
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Who cites it
13 citing papers in PubMed.
- One-step synthesis of 2-arylindoles from indolinesRSC advances · 2025Article
- Solventless Catalytic C-H and C-X Functionalization without Ball Milling.The Journal of organic chemistry · 2025Article
- Derivatization of 2,1,3-Benzothiadiazole via Regioselective C-H Functionalization and Aryne Reactivity.The Journal of organic chemistry · 2024Article
- Unleash electron transfer in C-H functionalization by mesoporous carbon-supported palladium interstitial catalysts.National science review · 2021Article
- Mechanochemical Solvent-Free Catalytic C-H Methylation.Angewandte Chemie (International ed. in English) · 2021Article
- C7-Indole Amidations and Alkenylations by Ruthenium(II) Catalysis.Angewandte Chemie (International ed. in English) · 2020Article
- Facile Synthesis of NH-Free 5-(Hetero)Aryl-Pyrrole-2-Carboxylates by Catalytic C-H Borylation and Suzuki Coupling.Molecules (Basel, Switzerland) · 2020Article
- Catalytic Au(i)/Au(iii) arylation with the hemilabile MeDalphos ligand: unusual selectivity for electron-rich iodoarenes and efficient application to indoles.Chemical science · 2019Article
- A comprehensive overview of directing groups applied in metal-catalysed C-H functionalisation chemistry.Chemical Society reviews · 2018Review
- Transition-Metal Catalyst Free Oxidative Radical Arylation ofACS omega · 2017Article
- Highly chemoselective ruthenium(ii)-catalyzed direct arylation of cyclic andChemical science · 2017Article
- Ru-Catalyzed C-H Arylation of Fluoroarenes with Aryl Halides.Journal of the American Chemical Society · 2016Article
- Crystal structure of aceto-nitrile-[η(6)-1-methyl-4-(1-methyl-eth-yl)benzene][1-(pyrimidin-2-yl)-3H-indol-1-ium-2-yl-κ(2) N,C]ruthenium(II) bis-(hexa-fluorido-anti-monate).Acta crystallographica. Section E, Crystallographic communications · 2015Article
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5 authors.
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Abstract
The Ru-catalysed C2-H arylation of indoles and pyrroles by using boronic acids under oxidative conditions is reported. This reaction can be applied to tryptophan derivatives and tolerates a wide range of functional groups on both coupling partners, including bromides and iodides, which can be further derivatised selectively. New indole-based ruthenacyclic complexes are described and investigated as possible intermediates in the reaction. Mechanistic studies suggest the on-cycle intermediates do not possess a para-cymene ligand and that the on-cycle metalation occurs through an electrophilic attack by the Ru centre.
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