ArticleCombustion and flame2013
Paramagnetic centers in particulate formed from the oxidative pyrolysis of 1-methylnaphthalene in the presence of Fe(III)
Article in Combustion and flame, 2013. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
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Who cites it
5 citing papers in PubMed.
- Laser-Powered Homogeneous Pyrolysis (LPHP) of Lignin Dispersed into Gas Phase.Molecules (Basel, Switzerland) · 2025Article
- Environmentally persistent free radicals: Methods for combustion generation, whole-body inhalation and assessing cardiopulmonary consequences.Environmental pollution (Barking, Essex : 1987) · 2023Article
- Investigation of resonance-stabilized radicals associated with soot particle inception using advanced electron paramagnetic resonance techniques.Communications chemistry · 2023Article
- Metal-Free Biomass-Derived Environmentally Persistent Free Radicals (Bio-EPFRs) from Lignin Pyrolysis.ACS omega · 2022Article
- Speciation of Iron (III) Oxide Nanoparticles and Other Paramagnetic Intermediates during High-Temperature Oxidative Pyrolysis of 1-Methylnaphthalene.World academy of science, engineering and technology · 2015Article
Corrections and comments
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4 authors.
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Abstract
The identity of radical species associated with particulate formed from the oxidative pyrolysis of 1-methylnaphthalene (1-MN) was investigated using low temperature matrix isolation electron paramagnetic resonance spectroscopy (LTMI-EPR), a specialized technique that provided a method of sampling and analysis of the gas-phase paramagnetic components. A superimposed EPR signal was identified to be a mixture of organic radicals (carbon and oxygen-centered) and soot. The carbon-centered radicals were identified as a mixture of the resonance-stabilized indenyl, cyclopentadienyl, and naphthalene 1-methylene radicals through the theoretical simulation of the radical's hyperfine structure. Formation of these radical species was promoted by the addition of Fe(III)
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