Evidence map›Paper›PMID 25670990›Full record

ArticleBeilstein journal of organic chemistry2015

Efficient deprotection of F-BODIPY derivatives: removal of BF2 using Brønsted acids.

Mingfeng Yu, Joseph K-H Wong, Cyril Tang, Peter Turner, Matthew H Todd, Peter J Rutledge

Open access · diamondAbstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Beilstein journal of organic chemistry, 2015. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.

0numbers the graph read from it
0cells of the map it votes in
9citing papers in PubMed
2.4field-weighted citation impact, top 11% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

9 citing papers in PubMed, 34 citations in OpenAlex.

  1. A π-extended β-diketiminate ligandChemical communications (Cambridge, England) · 2024
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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors at 1 institution in 1 country.

Mingfeng YuSchool of Chemistry, The University of Sydney, Sydney, New South Wales 2006, Australia.
Joseph K-H WongSchool of Chemistry, The University of Sydney, Sydney, New South Wales 2006, Australia.
Cyril TangSchool of Chemistry, The University of Sydney, Sydney, New South Wales 2006, Australia.
Peter TurnerCrystal Structure Analysis Facility, School of Chemistry, The University of Sydney, Sydney, New South Wales 2006, Australia.
Matthew H ToddSchool of Chemistry, The University of Sydney, Sydney, New South Wales 2006, Australia.
Peter J RutledgeSchool of Chemistry, The University of Sydney, Sydney, New South Wales 2006, Australia.
University of Sydney · AU

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The effective and efficient removal of the BF2 moiety from F-BODIPY derivatives has been achieved using two common Brønsted acids; treatment with trifluoroacetic acid (TFA) or methanolic hydrogen chloride (HCl) followed by work-up with Ambersep(®) 900 resin (hydroxide form) effects this conversion in near-quantitative yields. Compared to existing methods, these conditions are relatively mild and operationally simple, requiring only reaction at room temperature for six hours (TFA) or overnight (HCl).

Indexed as

Brønsted acidsclick chemistrydeborationdipyrrinsF-BODIPYs

Identifiers

PMID25670990
PMCPMC4311716
OpenAlexW1985030531

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.