ArticleChemical communications (Cambridge, England)2015
N-Heterocyclic carbene-catalyzed enantioselective annulations: a dual activation strategy for a formal [4+2] addition for dihydrocoumarins.
Article in Chemical communications (Cambridge, England), 2015. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.
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Who cites it
10 citing papers in PubMed, 112 citations in OpenAlex.
- A Novel Method to Construct 2-Aminobenzofurans via [4 + 1] Cycloaddition Reaction of In Situ GeneratedMolecules (Basel, Switzerland) · 2022Article
- Single-electron Carbene Catalysis in Redox Processes.Trends in chemistry · 2022Article
- Combined Photoredox and Carbene Catalysis for the Synthesis of γ-Aryloxy Ketones.Advanced synthesis & catalysis · 2022Article
- Recent advances of N-heterocyclic carbenes in the applications of constructing carbo- and heterocyclic frameworks with potential biological activity.RSC advances · 2021Review
- NHC-catalyzed enantioselective synthesis of β-trifluoromethyl-β-hydroxyamides.Beilstein journal of organic chemistry · 2020Article
- A tandem dearomatization/rearomatization strategy: enantioselective N-heterocyclic carbene-catalyzed α-arylation.Chemical science · 2019Article
- Enantioselective Phenolic α-Oxidation Using HJournal of the American Chemical Society · 2019Article
- Cyclopentyl Methyl Ether: An Elective Ecofriendly Ethereal Solvent in Classical and Modern Organic Chemistry.ChemSusChem · 2019Review
- A novel dihydrocoumarin under experimental and theoretical characterization.Journal of molecular modeling · 2017Article
- The Emergence of Quinone Methides in Asymmetric Organocatalysis.Molecules (Basel, Switzerland) · 2015Review
Corrections and comments
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Authors and funding
2 authors at 1 institution in 1 country.
Funding
Abstract
A highly efficient asymmetric formal [4+2] annulation for the synthesis of dihydrocoumarins has been developed via an in situ activated NHC catalysis. Both electrophilic and nucleophilic species are generated in situ simultaneously whereby acyl imidazoles facilitated rapid formation of an NHC-enolate intermediate to afford the [4+2] dihydrocoumarin adducts.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.