ArticleACS photonics2014
Nonlinear Midinfrared Photothermal Spectroscopy Using Zharov Splitting and Quantum Cascade Lasers.
Article in ACS photonics, 2014. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
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Who cites it
9 citing papers in PubMed.
- Biological and Biomedical Applications of Optical Photothermal Infrared Spectroscopy (O-PTIR).Applied spectroscopy · 2026Review
- Thermal transport across membranes and the Kapitza length from photothermal microscopy.Journal of biological physics · 2023Article
- Design Considerations for Discrete Frequency Infrared Microscopy Systems.Applied spectroscopy · 2021Article
- Bond-selective imaging by optically sensing the mid-infrared photothermal effect.Science advances · 2021Review
- Photoswitchable Spasers with a Plasmonic Core and Photoswitchable Fluorescent Proteins.Scientific reports · 2019Article
- Ultrafast chemical imaging by widefield photothermal sensing of infrared absorption.Science advances · 2019Article
- Bond-selective transient phase imaging via sensing of the infrared photothermal effect.Light, science & applications · 2019Article
- Spaser as a biological probe.Nature communications · 2017Article
- Depth-resolved mid-infrared photothermal imaging of living cells and organisms with submicrometer spatial resolution.Science advances · 2016Article
Corrections and comments
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Authors and funding
7 authors.
Funding
Abstract
We report on the mid-infrared nonlinear photothermal spectrum of the neat liquid crystal 4-octyl-4'-cyanobiphenyl (8CB) using a tunable Quantum Cascade Laser (QCL). The nonequilibrium steady state characterized by the nonlinear photothermal infrared response undergoes a supercritical bifurcation. The bifurcation, observed in heterodyne two-color pump-probe detection, leads to ultrasharp nonlinear infrared spectra similar to those reported in the visible region. A systematic study of the peak splitting as a function of absorbed infrared power shows the bifurcation has a critical exponent of 0.5. The observation of an apparently universal critical exponent in a nonequilibrium state is explained using an analytical model analogous of mean field theory. Apart from the intrinsic interest for nonequilibrium studies, nonlinear photothermal methods lead to a dramatic narrowing of spectral lines, giving rise to a potential new contrast mechanism for the rapidly emerging new field of mid-infrared microspectroscopy using QCLs.
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Registered trials
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