ArticleInorganic chemistry2015
Investigations of the effect of the non-manganese metal in heterometallic-oxido cluster models of the oxygen evolving complex of photosystem II: lanthanides as substitutes for calcium.
Article in Inorganic chemistry, 2015. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 20 papers.
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Who cites it
20 citing papers in PubMed.
- Tailoring Alginate Hydrogels via Precoordinated Lanthanide Complexes as Dynamic Cross-Linkers.Biomacromolecules · 2026Article
- Iron promoted end-on dinitrogen-bridging in heterobimetallic complexes of uranium and lanthanides.Chemical science · 2024Article
- Redox Processes Involving Oxygen: The Surprising Influence of Redox-Inactive Lewis Acids.JACS Au · 2024Review
- Structural distortion by alkali metal cations modulates the redox and electronic properties of CeChemical science · 2023Article
- Structural and energetic insights into Mn-to-Fe substitution in the oxygen-evolving complex.iScience · 2023Article
- Ultrasonic Clusterization Process to Prepare [(NNCO)ACS omega · 2022Article
- Mimicking the Oxygen-Evolving Center in Photosynthesis.Frontiers in plant science · 2022Review
- Integration of bio-inspired lanthanide-transition metal cluster and P-doped carbon nitride for efficient photocatalytic overall water splitting.National science review · 2021Article
- CaMnAngewandte Chemie (International ed. in English) · 2021Article
- Role of redox-inactive metals in controlling the redox potential of heterometallic manganese-oxido clusters.Photosynthesis research · 2021Article
- Influence of a Lanthanide Ion on the Ni Site of a Heterobimetallic 3d-4f Mabiq Complex.Inorganic chemistry · 2021Article
- Electronic Consequences of Ligand Substitution at Heterometal Centers in Polyoxovanadium Clusters: Controlling the Redox Properties through Heterometal Coordination Number.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
- Redox Tuning via Ligand-Induced Geometric Distortions at a YMnInorganic chemistry · 2019Article
- Bimetallic nickel-lutetium complexes: tuning the properties and catalytic hydrogenation activity of the Ni site by varying the Lu coordination environment.Chemical science · 2019Article
- Effects of Lewis Acidic Metal Ions (M) on Oxygen-Atom Transfer Reactivity of Heterometallic MnInorganic chemistry · 2019Article
- Thermodynamics of Proton and Electron Transfer in Tetranuclear Clusters with Mn-OHJournal of the American Chemical Society · 2018Article
- Incorporation of redox-inactive cations promotes iron catalyzed aerobic C-H oxidation at mild potentials.Chemical science · 2018Article
- Models for Unsymmetrical Active Sites in Metalloproteins: Structural, Redox, and Magnetic Properties of Bimetallic Complexes with MInorganic chemistry · 2017Article
- Effect of the Mn Oxidation State on Single-Molecule-Magnet Properties: Mn(III) vs Mn(IV) in Biologically Inspired DyMn3O4 Cubanes.Inorganic chemistry · 2016Article
- Toward models for the full oxygen-evolving complex of photosystem II by ligand coordination to lower the symmetry of the Mn3CaO4 cubane: demonstration that electronic effects facilitate binding of a fifth metal.Journal of the American Chemical Society · 2014Article
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Abstract
We report the syntheses and electrochemical properties of nine new clusters ([LLnMn(IV)3O4(OAc)3(DMF)n](+) (Ln = La(3+), Ce(3+), Nd(3+), Eu(3+), Gd(3+), Tb(3+), Dy(3+), Yb(3+), and Lu(3+), n = 2 or 3)) supported by a ligand (L(3-)) based on a 1,3,5-triarylbenzene motif appended with alkoxide and pyridine donors. All complexes were obtained by metal substitution of Ca(2+) with lanthanides upon treatment of previously reported LMn3CaO4(OAc)3(THF) with Ln(OTf)3. Structural characterization confirmed that the clusters contain the [LnMn3O4] cubane motif. The effect of the redox-inactive centers on the electronic properties of the Mn3O4 cores was investigated by cyclic voltammetry. A linear correlation between the redox potential of the cluster and the ionic radii or pKa of the lanthanide metal ion was observed. Chemical reduction of the LMn(IV)3GdO4(OAc)3(DMF)2 cluster with decamethylferrocene, resulted in the formation of LGdMn(IV)2Mn(III)O4(OAc)3(DMF)2, a rare example of mixed-valence [MMn3O4] cubane. The lanthanide-coordinated ligands can be substituted with other donors, including water, the biological substrate.
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