Evidence map›Paper›PMID 25492109›Full record

ArticleScientific reports2014

Complete mineralization of perfluorooctanoic acid (PFOA) by γ-irradiation in aqueous solution.

Ze Zhang, Jie-Jie Chen, Xian-Jin Lyu, Hao Yin, Guo-Ping Sheng

Open access · goldAbstract read
In one paragraph

Article in Scientific reports, 2014. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.

0numbers the graph read from it
0cells of the map it votes in
7citing papers in PubMed
5.6field-weighted citation impact, top 5% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

7 citing papers in PubMed, 126 citations in OpenAlex.

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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors at 1 institution in 1 country.

Ze ZhangCAS Key Laboratory of Urban Pollutant Conversion, Department of Chemistry.
Jie-Jie ChenCAS Key Laboratory of Urban Pollutant Conversion, Department of Chemistry.
Xian-Jin LyuCAS Key Laboratory of Urban Pollutant Conversion, Department of Chemistry.
Hao YinHefei National Laboratory for Physical Sciences at Microscale, University of Science and Technology of China, Hefei, 230026, China.
Guo-Ping ShengCAS Key Laboratory of Urban Pollutant Conversion, Department of Chemistry.
Hefei National Center for Physical Sciences at Nanoscale · CN

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Decomposition of perfluorooctanoic acid (C7F15COOH, PFOA) has been gaining increasing interests because it is a ubiquitous environmental contaminant and resistant to the most conventional treatment processes. In this work, the rapid and complete mineralization of PFOA and simultaneous defluorination were achieved by γ-ray irradiation with a (60)Co source. The degradation rate of PFOA by γ-ray irradiation would be high, and a pseudo-first-order kinetic rate constant of 0.67 h(-1) could be achieved in the N2 satured condition at pH 13.0. The experimental results and quantum chemical calculation confirmed that two radicals, i.e., hydroxyl radical (·OH) and aqueous electrons (eaq(-)), were responsible for the degradation of PFOA, while only either eaq(-) or ·OH might not be able to accomplish complete mineralization of PFOA. The synergistic effects of ·OH and eaq(-) involved in the cleavage of C-C and C-F bonds, and therefore complete mineralization of PFOA were achieved. The intermediate products were identified and the degradation pathway was also proposed. The results of this study may offer a useful, high-efficient approach for complete mineralizing fluorochemicals and other persistent pollutants.

Indexed as

Gamma RaysCaprylatesFluorocarbonsHydroxyl RadicalCaprylatesFluorocarbonsHydroxyl Radicalperfluorooctanoic acid

Identifiers

PMID25492109
PMCPMC4261166
OpenAlexW1965820562

What OpenQuestion holds

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LicenceCC BY-NC-SA
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.